SOIL CHEMISTRY Flashcards

1
Q

[] is generally more available in neutral to slightly alkaline soils, while [] is more available in acidic conditions.

A
  1. Nitrogen (N) - nitrate, ammonium
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2
Q

The rate of many chemical reactions, including those involving soil minerals and organic matter, is []. For instance, acid-base reactions are more favorable in certain pH ranges, affecting the transformation of nutrients.

A

pH-dependent

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3
Q

comprises the inorganic components of soil, primarily derived from weathered rocks.

A

mineral matter

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4
Q

The ability of soil to support loads is a critical factor in engineering. Different
soil types have varying load-bearing capacities, which must be assessed
during the design phase. For instance, [] can expand and contract, impacting structures, while [] may provide better drainage but lower load support.

A

Load-Bearing Capacity
clay soils
sandy soils

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5
Q

Multifunctional Roles of Soil

A
  1. Agricultural Productivity
  2. Infrastructure Development
  3. Ecological Balance
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6
Q

Other Remediation Techniques
Additional methods for cleaning contaminated soils include:

A

i. Soil Washing: Physically removing contaminants through water or chemical solutions, washing away pollutants while leaving soil structure intact.
i. Thermal Treatment: Heating contaminated soil to volatilize and
destroy organic pollutants.
ii. Chemical Oxidation: Applying chemical agents to oxidize and break down contaminants.

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7
Q

Heating contaminated soil to volatilize and
destroy organic pollutants.

A

thermal treatment

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8
Q

Different microorganisms thrive at different pH levels. A [] pH is generally
favorable for a wide variety of microbes, whereas [] conditions may limit microbial diversity

A

neutral
highly acidic or alkaline

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9
Q

Good aeration is essential for root respiration and microbial activity.
[] soils typically allow for better aeration compared to [] soils, which can become compacted and restrict air flow.

A

sandy
clay

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10
Q

industrial wastes

A

i. Manufacturing Facilities: Factories may release heavy metals (e.g., lead, mercury), solvents, and other toxic compounds into the soil through spills, leaks, or improper
disposal.
ii. Mining Operations: Mining can lead to soil contamination from heavy metals and acidic runoff, affecting surrounding
ecosystems.
iii. Construction Sites: Construction debris, concrete, and hazardous materials can contribute to soil pollution.

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11
Q

Elements like iron (Fe), manganese (Mn), and zinc (Zn) become more available in acidic soils but may become deficient in alkaline conditions.

A
  1. Micronutrients:
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12
Q

Applying chemical agents to oxidize and
break down contaminants.

A

chemical oxidation

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13
Q

Physically removing contaminants through water or chemical solutions

A

Soil Washing

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14
Q

a process that utilizes living organisms, primarily microorganisms, to degrade or transform contaminants in the soil. Key
aspects include:

A

bioremediation

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15
Q

High fertilizer use can lead to the accumulation of salts in the soil, adversely affecting soil structure and fertility.

A

ii. Salinization:

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16
Q

Composition of Soil

A

Mineral Matter
Organic Matter
Water and Air

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17
Q

resulting from decomposed plant and animal materials, enriches the soil by improving fertility, moisture retention,
and microbial activity. It plays a vital role in nutrient cycling and enhances soil structure.

A

organic matter

18
Q

[]: [] particles ([] mm) that have high nutrient retention and water-holding capacity but can lead to drainage issues.

A

clay: Fine
<0.002

19
Q

The metabolic rates of bacteria and fungi are affected by pH, influencing their efficiency in breaking down organic matter and cycling nutrients. For example, some nitrogen-fixing bacteria prefer slightly acidic conditions.

A

Microbial Activity:

20
Q

Rain or irrigation can wash pesticides from fields into nearby soils and water bodies, leading to broader environmental impacts.

A

ii. Runoff:

21
Q

[] is a measure of the acidity or alkalinity of the soil, expressed on a logarithmic scale ranging from 0 to 14, where:

pH < 7:
pH = 7:
pH > 7:

A

Soil pH
acidic
neutral
alkaline

22
Q

Sources of Soil Contamination

A

industrial wastes
pesticides
fertilizer

23
Q

pesticides

A

i. Direct Application: Overuse or improper application of pesticides can result in residues remaining in the soil, affecting
microbial life and plant health
ii. Runoff: Rain or irrigation can wash pesticides from fields into nearby soils and water bodies, leading to broader environmental impacts.

24
Q

[] can lead to soil contamination from heavy metals and acidic runoff, affecting surrounding ecosystems.

A

ii. Mining Operations:

25
Q

Factories may release heavy metals (e.g., lead, mercury), solvents, and other toxic compounds into the soil through spills, leaks, or improper disposal.

A

i. Manufacturing Facilities:

26
Q

Soil contains [] in the spaces between soil particles, which is essential for plant growth and microbial activity. Air is also crucial, as it provides oxygen for roots and microorganisms. The balance of water and air in soil affects its physical properties and overall health.

A

water

27
Q

Construction debris, concrete, and hazardous materials can contribute to soil pollution.

A

iii. Construction Sites:

28
Q

Nitrogen and phosphorus from fertilizers can leach into the soil and waterways, causing eutrophication and altering soil chemistry.

A

i. Nutrient Runoff:

29
Q

[] particles have a larger surface area and can hold more nutrients than sand, making them more fertile. However, [] soils may require more frequent fertilization due to their lower nutrient-holding capacity

A

clay
sandy

30
Q

Certain nutrients, such as [] and [], become more soluble and available to plants in acidic conditions, while others, like [], can become less available due to precipitation in alkaline soils.

A

iron and manganese
phosphorus

31
Q

Contaminated soil is excavated and treated elsewhere, often requiring controlled conditions.

A

microbial action: ex situ

32
Q

Highly reactive and can form insoluble compounds, particularly in alkaline soils (pH > 7). Maintaining a slightly acidic to neutral pH (around 6-7) enhances [] availability.

A
  1. Phosphorus (P)
33
Q

[]: [] particles ([] to [] mm) that provide good drainage and aeration but have low nutrient retention

A

sand: coarse
0.05 to 2

34
Q

Typically remains relatively available across a wide pH range, but extreme pH levels can affect its uptake due to changes in soil structure and microbial activity.

A
  1. Potassium (K)
35
Q

Soil texture plays a critical role in determining how water moves through
the soil. [] soils drain quickly, which can be beneficial in preventing waterlogging but may require more frequent irrigation. [] soils retain water longer, which can lead to saturation and reduced aeration.

A

Drainage
Sandy
Clay

36
Q

[] refers to the gradual sinking of structures as the underlying soil compresses under load. Understanding the compressibility of different soil types helps engineers design foundations that minimize [] and ensure structural integrity

A

Settlement

37
Q

the use of plants to absorb, accumulate, and detoxify contaminants from the soil. The plants can uptake heavy metals and organic pollutants through their roots and either store them in their tissues or transform them into less harmful forms.

A

phytoremediation

38
Q

Treatment occurs on-site, allowing for natural conditions to be maintained

A

microbial action: in situ

39
Q

[]: [] particles ([] to [] mm) that hold moisture well and provide moderate fertility.

A

silt: medium
0.002 to 0.05

40
Q

fertilizers

A

i. Nutrient Runoff: Nitrogen and phosphorus from fertilizers can leach into the soil and waterways, causing eutrophication and altering soil chemistry.
ii. Salinization: High fertilizer use can lead to the accumulation of salts in the soil, adversely affecting soil structure and fertility.

41
Q

Overuse or improper application of pesticides can result in residues remaining in the soil, affecting microbial life and plant health

A

i. Direct Application: