Shapes Of Molecules And Intermolecular Forces Ch. 7 Flashcards

1
Q

What happens to electron pairs in outer shells

A

They repel each other and end up as far apart as geometrically possible.

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2
Q

Which are stronger lone or bond pairs

A

Lone pairs

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3
Q

Rule for electron repulsion theory

A

Lone pair:lone pair repulsion > lone pair:bond pair repulsion> bond pair:bond pair repulsion

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4
Q

Linear have a bond angle of

A

180°

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5
Q

Trigonal planar have a bond angle of

A

120°

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6
Q

Tetrahedral has a bond angle of

A

109.5°

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7
Q

Pyramidal has a bond angle of

A

107°

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8
Q

V-Shaped has a bond angle of

A

104.5°

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9
Q

Two bond pairs, no lone pairs

A

Linear

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10
Q

Three bond pairs, no lone pairs

A

Trigonal planar

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11
Q

4 bond pairs, no lone pairs

A

Tetrahedral

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12
Q

Three bond pairs, one lone pair

A

Pyramidal

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13
Q

Two bond pairs, two lone pairs

A

V-Shaped

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14
Q

What two criteria are there for a molecule to be polar

A

Polar covalent bonds, no symmetry

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15
Q

Which shapes of molecules are described to be non-polar and why

A

Linear, trigonal planar, tetrahedral due to their symmetry

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16
Q

What is intramolecular bonding

A

The forces within the molecule holding the atoms together

17
Q

What are intermolecular forces

A

Forces between molecules

18
Q

What are the three types of intermolecular forces from strongest to weakest

A

Hydrogen bonds, dipole dipole forces, van der Waals’ forces

19
Q

Define hydrogen bonding

A

special type of dipole dipole forces that only occurs between hydrogen and small, highly electronegative elements such as O, N and F.

20
Q

What is determined by the intermolecular forces

A

Boiling point (H-bonds = higher, van der Waals’ = Lower)