Ionic And Covalant Bonding Ch. 6 Flashcards
What is water crystallisation
Water that is chemically combined in definite proportions in a crystalline compound
What is the octet rule
All atoms are looking to have a full outer shell of 8 electrons
Hydroxide
OH-
Carbonate
CO3 2-
Nitrate
NO3 -
Hydrogencarbonate
HCO3-
Sulfite
SO3 2-
Sulfate
SO4 2-
Phosphate
PO4 3-
Dichromate
Cr2O7 2-
Ethanoate
CH3COO -
Ammonium
NH4 +
Manganate(VII)
MnO4 -
Chromate
CrO4 -
Exceptions to the octet rule
Beryllium and boron do not have enough electrons in their outer shell to get 8 electrons, d-block elements don’t obey the rule Hydrogen and lithium tend to reach the electronic structure of helium.
What is an ionic bond
The electrostatic force of attraction between oppositely charged ions
What do iconic bonds form
Three dimensional lattice structures
What is a covalent bond
Formed when two atoms share a pair of electrons
What is sigma bonding
Involves the end on overlap of p-orbitals and s-orbitals, stronger than pi bonding and occurs first
What are pi bonds
Involves the side on overlap of p-orbitals, forms the 2nd and 3rd bond and is weaker than sigma bonds
What kind of bond occurs when two oxygen atoms bond
Pure covalent bond, forms a molecule of oxygen (O2)
Define electronegativity
The relative attraction of an atom for shared pairs of electrons in a covalent bond
What three factors affect the electronegativity of an element
Nuclear charge, atomic radius, screening effect
General trend for electronegativity across a period
Electronegativity increases due to a larger nuclear charge and a smaller atomic radius
General trend for electronegativity down a group
Electronegativity decreases due to an increase in the screening effect and an increase in atomic radius
Electronegativity difference < 1.7
Polar covalant
Electronegativity difference < 0.4
Covalant (slight polarity)
Electronegativity difference > 1.7
Ionic
Properties of Ionic compounds
High melting point, conduct electricity when molten or in an aqueous solution, hard solids
Properties of covalent compounds
Low melting points, do not conduct electricity in the liquid state, are gases, liquids or soft solids
How do you purify covalent compounds
Via recrystallization