Separate Chemistry 2 Flashcards

1
Q

Homologous series definition

A

Group of chemicals with similar chemical structures

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2
Q

Alkane general formula

A

CnH2n+2

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3
Q

Functional group of alkenes

A

C=C

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4
Q

Why are alkenes unsaturated?

A

Double bonds are present and can open up and bond further

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5
Q

How to test for alkenes

A

Add orange bromine water to alkene and shake
If bromine water becomes colourless, alkenes are present
Addition reaction has occurred

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6
Q

Complete combustion of hydrocarbons word equation

A

Hydrocarbon + oxygen -> carbon dioxide + water

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7
Q

Addition polymerisation method

A

Lots of unsaturated smaller monomers open up their double bonds
They join together to form polymer chains

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8
Q

Propane as a polymer symbol

A

(C3H6)n

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9
Q

Formula for alkenes

A

CnH2n

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10
Q

Properties of poly(ethene)

A

Flexible
Electrical insulator
Cheap

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11
Q

Properties of poly(propene)

A

Flexible
Strong
Tough
Mouldable

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12
Q

Properties of poly(chloroethene) (PVC)

A

Tough

Cheap

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13
Q

Properties of poly(tetrafluoroethene) (PTFE)

A

Un reactive
Tough
Non-stick

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14
Q

Uses of poly(ethene)

A

Plastic bags, bottled, wire insulation

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15
Q

Uses of poly(propene)

A

Crates
Furniture
Ropes

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16
Q

Uses of poly(chloroethene) (PVC)

A

Window frames

Water pipes

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17
Q

Uses of poly(tetrafluoroethene) (PTFE)

A

Non-stick pans

Waterproof clothing

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18
Q

Condensation polymerisation method

A

Involves 2 different types of monomers
Each monomer contains at least 2 functional groups
Each functional group reacts with the functional group of another monomer, creating long chains of alternating monomers
Small molecule is lost per new bond made (e.g. water)

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19
Q

Polyester method

A

Dicarboxylic acid monomers contain 2 carboxylic acid (-COOH) groups
Diol monomers contain 2 alcohol groups (-OH) groups
Carboxylic acid groups react with alcohol groups to form an ester link
Molecule of water is lost per ester link made
Type of condensation polymerisation

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20
Q

Important naturally occurring monomers

A

Nucleotides -> DNA
Amino acid -> proteins and enzymes
Carbohydrates -> starch and cellulose

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21
Q

General formula for alcohols

A

CnH2n+1OH

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22
Q

Alcohol functional group

A

(-OH)

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23
Q

General formula for carboxylic acids

A

Cn-1H2n-1COOH

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24
Q

carboxylic acid functional group

A

(-COOH)

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25
Fermentation formula
C6H12O6 -> yeast -> 2C2H5OH + 2CO2 | Glucose -> yeast -> ethanol + carbon dioxide
26
Fermentation process
Carbohydrate (from sugar cane or sugar beet) is used Yeast cells are mixed carbohydrate in clean container Mixture is sealed and stored in a warm place (ideally between 30°C - 40°C) Must have no oxygen present (oxidised ethanol turns into ethanoic acid) Alcohol concentration gets high enough to kill off yeast Distill mixture to get more concentrated alcohol
27
How to make concentrated ethanol
Fractional distillation Ethanol has lower boiling point so will evaporate before water This can then condense and be collected in a beaker while water stays as a liquid
28
Colour flame turns with lithium ions
Crimson red
29
Colour flame turns with calcium ions
Orange-red
30
Colour flame turns with sodium ions
Yellow
31
Colour flame turns with copper ions
Blue-green
32
Colour flame turns with potassium ions
Lilac (purple)
33
How to carry out flame test
Clean nichrome wire loop by dipping into hydrochloric acid and rinsing with distilled water Dip wire loop into sample of metal compound Place loop in clear blue part of Bunsen burner
34
How to test for cations with precipitates
Add sodium hydroxide solution to compound | If hydroxide precipitate forms, colour correlates to metal ion in compound
35
Colour of precipitate made with sodium hydroxide solution + aluminium
White at first then dissolves in excess NAOH to form colourless solution
36
Colour of precipitate made with sodium hydroxide solution + calcium
White
37
Colour of precipitate made with sodium hydroxide solution + copper
Blue
38
Colour of precipitate made with sodium hydroxide solution + iron
Green if Fe2+ | Brown if Fe3+
39
How to test for ammonium ions (NH4 +)
Add sodium hydroxide solution to mystery solution Hold damp red litmus paper over solution If paper turns blue, ammonia is present
40
How to test for halide ions
Add nitric acid Add silver nitrate solution Check colour of precipitate
41
Colour of precipitate made with silver nitrate + chloride
White (silver chloride)
42
Colour of precipitate made with silver nitrate + bromide
Cream (silver bromide)
43
Colour of precipitate made with silver nitrate + iodide
Yellow (silver iodide)
44
How to test for carbonates
Add dilute acid Fizzes if carbonate is present (carbon dioxide) Use limewater to test for carbon dioxide
45
How to test for sulfate ions
Add dilute hydrochloric acid to stop precipitation reactions not involving sulfate ions Add barium chloride solution If sulfate ions present, precipitate made will be white (barium sulfate)
46
Why each ion test has to be unique
If each test gave the same response, ions present wouldn’t be able to be differentiated from each other
47
How flame photometry works
Each ion produced a unique line spectrum (how to identify what ion) Intensity of measured wavelength correlates to ion’s concentration Also can be used in mixtures
48
Advantages of machines in instrumental analysis
``` Very sensitive (can detect tiniest amounts of substance) Very fast (can be automated) Very accurate (no human error) ```
49
Disposal of polymers in landfills facts
Done because polymers are too difficult or expensive to separate and recycle Valuable land is used up as landfill sites Polymers are non-biodegradable so they will stay in landfill for thousands of years
50
Disposal of polymers by combustion facts
Burning plastics produces a lot of heat and can be used to generate electricity Toxic gases can be released from combustion of plastics Carbon dioxide produced can contribute to global warming
51
Advantages of recycling polymers
Reduces amount of non-biodegradable waste on landfill sites Reduces emissions of greenhouse and toxic gases from burning polymers Generally uses less water and energy resources than making new plastics Reduces amount of crude oil needed to produce more plastics Germany saves money and creates jobs
52
Disadvantages of recycling
Separating polymers can be difficult and expensive Quality of final recycled polymer reduced if polymers are mixed together Polymers can only be recycled a certain amount of times Melting down polymers can release dangerous gases
53
How to check which alcohol is best as a fuel
Put some alcohol in a spirit burner and measure mass Put 100cm3 of distilled water into a copper calorimeter Insulate calorimeter with drought excluder Place thermometer into calorimeter and cover with insulating lid Record initial temperature of water and light wick Stir water through using thermometer When temperature of water rises to 20°C, blow out spirit burner Reweigh burner and fuel Repeat with other alcohols
54
Nanoparticles definition
Particles 1-100 manometers across | Have different properties from the “bulk” chemical it’s made from due to a high surface area to volume ratio
55
Uses of nanoparticles
Good catalysts (higher surface area = more collisions) Cosmetics e.g. sunscreen (don’t leave white marks on skin) Nanomedicine (tiny fullerenes can deliver drugs more easily than most particles) Lubricant Nanotubes for conducting electricity Enforcing plastics in sports equipment Silver nanoparticles added in medical equipment for antibacterial uses
56
Risks of nanoparticles
Their effect on the body aren’t fully understood e.g. some nanoparticles don’t break down easily can cause problems e.g. lung inflammation if breathed in
57
Use of high-density poly(ethene)
Strong and rigid so used in water pipes
58
Use of low-density poly(ethene)
Light and stretchy so used for plastic bags and squeezy bottles
59
Use of poly(styrene) foam
Packaging and thermal insulation
60
Use of heat-resistant polymers e.g. melamine and poly(propene)
Plastic kettled
61
Clay facts
Mineral formed from weather and decomposed rock Soft when dug up so can be moulded into different shapes Hardens when fired at high temperatures Used in pottery and as a building material
62
Glass facts
Transparent and strong Can be moulded when hot Brittle when thin Usually made when limestone, sand and sodium carbonate are melted together
63
Composite definition
Things made of one material (reinforcement) embedded in another (matrix/binder) Properties depend on properties of the materials it is made from
64
Properties of metal as a material
Good heat and electric conductor High density Malleable Can be mixed with other elements to form alloys
65
Advantages of polymers as a material
Very adaptable (often flexible and be moulded into almost any shape) Cheaper Thermal and electrical insulators
66
Disadvantages of polymers as a material
Degrade and break down over time (don’t last as long) | Hard to dispose of properly
67
Advantages of ceramics as a material
Electric and heat insulator Strong and hard-wearing Don’t degrade over time so they last longer
68
Disadvantages of ceramics as a material
Brittle and stiff | Dense
69
Advantages of metals as a material
Good conductor of heat and electricity Malleable Corrosion-resistant metals last for a very long time Less brittle (don’t shatter)
70
Disadvantages of metals as a material
``` Some metals corrode easily Less brittle (likely to deform) ```
71
Advantages of composites as a material
Can be made for specific purpose (properties purely rely on materials they are made from)
72
Disadvantages of composites as a material
Much more expensive than other materials