Fuels and Earth Science Flashcards
All fractions from crude oil
Gas Petrol Naphtha Kerosene Diesel oil Bitumen
Uses of gases
Domestic heating
Cooking
Uses of petrol
Fuel for cars
Uses for naphtha
Dilute heavy crude oil
Uses for kerosene
Fuel for aircraft
Uses for diesel oil
Fuel for trains and some cars
Uses for fuel oil
Fuel for large ships and some power stations
Uses for bitumen
Surface roads and roofs
Definition of homologous series
Family of molecules that have same general formula and similar chemical properties
Why do larger molecules have bigger MP / BP?
There are more intermolecular forces to break so more heat energy is needed to overcome these forces
Properties of shorter hydrocarbons
Easy to ignite
Usually gas at room temperature
Lower viscosity (runnier)
Properties of longer hydrocarbons
Liquid at room temperature
Harder to ignite
Higher viscosity (thicker)
Complete combustion of hydrocarbons
hydrocarbon + oxygen ->
carbon dioxide + water
Incomplete combustion of hydrocarbons
hydrocarbon + oxygen(deficient) ->
carbon monoxide + carbon particulates
Dangers of carbon monoxide
- can combine with haemoglobin in red blood cells, preventing oxygen circulating properly
- lack of oxygen supply to brain can leas to fainting, coma or death
Dangers of carbon particulates
- fine particles of carbon released into atmosphere falls down as soot
- soot reduces air quality, dirtying buildings and worsening respiratory problems
Dangers of sulfur dioxide
- made when impurities in fossil fuels are burned
- when mixed with clouds, this makes dilute sulfuric acid and falls as acid rain
- acid rain causes lakes to be more acidic, harming the wildlife
- it also kills trees, damages limestone and stone buildings and makes metal corrode
Dangers of nitrogen oxides
- made when nitrogen and oxygen react in the air (energy from combustion in cars)
- contributes to acid rain
- causes photochemical smog, causing breathing difficulties, headaches and tiredness
Pros of hydrogen fuel
Clean fuel
Renewable (comes from water)
Cons of hydrogen fuel
You need a special, expensive engine
Hydrogen needs to be manufactured and uses energy from another source which has pollutants
Hydrogen is hard to store
Definition of cracking
Splitting up of long chain hydrocarbons
Form of thermal decomposition
Used to gain products with more demand from larger, less demand products
Cracking method
- vaporised hydrocarbons pass over powdered catalyst
- the hydrocarbons split apart on the surface of the bits of catalyst
- creates a shorter alkane molecule and alkene
Phase 1 of atmosphere
- there was no atmosphere
- Earth was just a molten ball that eventually cooled to form a thin crust
- volcanoes continued to erupt, releasing carbon dioxide, steam and methane
- the Earth cooled down further and the water vapour condensed, forming oceans
- there was little oxygen
Phase 2 of atmosphere
- lots of early atmosphere dissolved into the ocean
- nitrogen was released into the atmosphere by denitrifying bacteria and ammonia reacting with oxygen
- nitrogen stayed in the atmosphere
- green plants evolved around Earth and removed CO2 as they photosynthesised and formed oxygen
- oxygen levels began to rise and most of CO2 is trapped in fossil fuels and sedimentary rocks