sc10, electrolysis (paper 1) Flashcards

1
Q

define electrolysis

A

when electrical energy from a direct current supply decomposes an electrolyte

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2
Q

define electrode

A

a rod made of metal/graphite which carries the current into or out of the electrode

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3
Q

define electrolyte

A

an ionic compound in a molten or dissolved in water state

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4
Q

what is the cathode

A

negative cathode

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5
Q

what is the anode

A

positive cathode

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6
Q

which electrode is the anion attracted to

A

anode

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7
Q

which electrode is the cation attracted to

A

cathode

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8
Q

at what electrode does reduction occur at

A

cathode

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9
Q

at what electrode does oxidation occur at

A

anode

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10
Q

in terms of electrons and oxygen, what happens in oxidation

A
  • gains oxygen
  • loses electrons
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11
Q

in terms of electrons and oxygen, what happens in reduction

A
  • loses oxygen
  • gains electrons
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12
Q

why can we only use electrolysis in liquids and solutions and not solids

A

the ions are free to move and carry the charge where as a solid cannot

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13
Q

what do we do befor electrolysing an insoluble ionic compound

A
  • purify (if needed)
  • mix with cryolite to lower melting point (if needed)
  • then melt it to molten state
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14
Q

what happens when the ion is conducted to the compatible electrode

A

they are discharged as neutral atoms (solid/gas/molten)

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15
Q

how do we use electrolysis on soluble ionic compounds

A

we can dissolve them in water

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16
Q

explain why using electrolysis on soluble ionic compounds is more complicated

A

water splits into hydroxide and hydrogen ions

17
Q

which electrode is hydroxide attracted to

A

anode

18
Q

which electrode is hydrogen attracted to

A

cathode

19
Q

does the cathode attract metal or non-metal

A

metal

20
Q

does the anode attract metal or non-metal

A

non-metal

21
Q

what determines which element will be discharged at the anode for aqueous solutions

A

hydroxide with always discharge unless a halide is present (fluoride, chloride, bromide, iodide)

22
Q

what determines which element will be discharged at the cathode for aqueous solutions

A

the least reactive ion will be discharged
metals less reactive than hydrogen are: copper, silver, gold, platinum