salt preparation Flashcards

1
Q

what are all soluble salts?

A

all sodium + potassium + ammonium + nitrate salts

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2
Q

which salts are all soluble except for lead (ii) and silver?

A

chloride + bromide + iodide salts

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3
Q

what sulfate salts are insoluble?

A

barium + lead (ii) + calcium

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4
Q

what are the only carbonates that are soluble?

A

group1 metals + ammonium carbonates

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5
Q

what are the only hydroxides that are soluble?

A

group 1 + calcium + barium hydroxides/oxides

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6
Q

what is the only soluble lead compound?

A

lead (ii) nitrate

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7
Q

how do you make an insoluble salt?

A

precipitation

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8
Q

how do you make a soluble salt with a soluble base/carbonate?

A

titration

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9
Q

how do you make a soluble salt with an insoluble base/carbonate?

A

reaction of acid with excess insoluble bcm

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10
Q

what is a precipitate?

A

a solid that forms in a solution

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11
Q

what conditions must be met to form a precipitate?

A

both reactants must be in aqueous solution + products must be insoluble in water

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12
Q

what is the equation that represents the precipitation method?

A

AB (aq) + CD (aq) -> AD (s) + CB (aq)

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13
Q

what do you do if the starting reagent is an insoluble substance?

A

be converted into a soluble salt before the precipitation react can take place

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14
Q

what are the two reactions that can be expected from the titration method?

A

acid + alkali -> salt + water
acid + carbonate -> salt + carbon dioxide + water

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15
Q

what kind of salts are produced by titration?

A

salts of very reactive metals + ammonium

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16
Q

what are the conditions to be met for titration to be used?

A

both reactants are soluble and both products are soluble

17
Q

why is an indicator used for titration?

A

there is no visible residue/undissolved solid reactants to indicate a complete reaction which may allow the salt to be contaminated with excess acid/base/carbonate

18
Q

on a pH graph, what is the point called where the pH reaches 7?

A

equivalence point

19
Q

what are the three reactions for reaction of acid with excess insoluble bcm?

A

acid + excess metal -> salt + hydrogen
acid + excess insoluble base -> salt + water
acid + excess onsoluble carbonatre -> salt + water + carbon dioxide

20
Q

why is excess of the bcm added to the acid?

A

to ensure that all the sulfuric acid will be used up and prevents the salt solution will be contaminated with the acid

21
Q

why is the mixture filtered?

A

to remove excess bcm

22
Q

why is the mixture heated to about half or one-third its original volume?

A

to form a saturated solution for crystallization to occur

23
Q

why is crystallization is used as opposed to heating to dryness?

A

heating to dryness would cause the salt to lose the water of crystallization

24
Q

why are the crystals wash with cold distilled water?

A

so it does not dissolve crystals but is able to remove soluble impurities

25
Q

why are crystals dried between sheets of filter paper?

A

prevent the loss of water of crystallisation

26
Q

what type of salts are made from reaction of acid with base or metal carbonate?

A

moderately reactive metals and unreactive metals