Salt analysis 3 Flashcards

1
Q

NH4+ present

A
  • Heat the given salt with NaOH.
    Smell of NH3
  • Bring a glass rod dipped in Conc. HCl near a mouth of the test tube.
    Dense white fumes evolves
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2
Q

NH4+ confirmed

A
  • Add Nesslers reagent to the salt solution.
    Brown ppt formed
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3
Q

CO32-
Present.

A
  • Treat the salt with dil. H2SO4 solution
    Observation: -
  • colourless and odourless gas with brisk effervescence evolve
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4
Q

S2- present

A
  • Treat the salt with dil. H2SO4 solution
    Observation: -
  • Colourless gas with smell of rotten egg turning lead acetate paper black.
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5
Q

Cl- present

A
  • Treat with con. H2SO4 solution
    Observation: -
  • Colourless gas with pungent smell giving dense white fumes with glass rod dipped in NH40H.
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6
Q

Br- present

A
  • Treat with con. H2SO4 solution
    Observation: -
  • Reddish brown vapour and solution turns brown
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7
Q

I- present

A
  • Treat with con. H2SO4 solution
    Observation: -
  • Violet vapour
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8
Q

NO3- present

A
  • Treat with con. H2SO4 solution
    Observation: -
  • Reddish brown vapour obtained on heating
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9
Q

Acetate present

A
  • Treat with con. H2SO4 solution
    Observation: -
  • Vinegar smell
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10
Q

(2) NO3- present

A
  • Treat with con. H2SO4 solution.
    Add Cu turning to the above solution(if Nitrate) and heat.
    Observation:-
  • Intense brown vapour evolves and solution turns blue.
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