Restorative Resin Based Composite Materials Flashcards
What’s the definition of a composite
Compound of 2 or more distinctly different materials with properties that are superior or intermediate to those of individual constituents
Are teeth composites
yes- the two materials are enamel and dentin
What is the organic matrix of enamel
enamelin
What is the inorganic matrix of enamel
hydroxyapatite
What is the organic matrix of dentin
collagen
what is the inorganic matrix of dentin
hydroxyapatite
What are the advantages of resin composite
- Esthetic (emulates tooth structure)
- Fracture resistant
- Wear resistance
- Command set- can sculpt and carve
- Conservative preparation (most important advantage)
- Low thermal conductivity (compared to amalgam)
- Radiopaque
What are the disadvantages of Resin Composite
- Polymerization shrink ~2-4%
- Requires dental bonding agents (DBA) and light curing (extra step)
- lengthy placement
- RD required
- Marginal leakage and wear resistance (these are no longer issues but they once were)
- Water sorption- Absorbs H2O causing discorloration and swelling of the restoration
What are the 4 structural components of resin composite
- polymer matrix
- Inorganic filler
- Coupling agent
- Initiator
What is an organic polymer matrix is a __phase to which other materials are __
a continuous phase…added
The organic polymer matrix is made out of
resin monomers
What are the highly viscous resin monomers (2)
Bis-GMA
UMDA
Bis-GMA and UMDA are (high/low) MW monomers
high
What are the low MW monomers with low viscosity
TEG-DMA and Bis-EMA
Which two monomers listed are low shrinking monomers
Bis-EMA and oxybismethacrylate
Inorganic fillers are __ or __ based
glass or quartz
What are the three most common inorganic fillers
zirconium oxide, aluminum oxide, and silicon dioxide
Filler particles are added to…
the organic matrix
Filler is added to the organic matrix in order to improve the
physical properties of the resin
In general the (greater/less) the filler the the better the properties of the resin- but there is a limit
greater
Why would excess filler lead to an unfavorable resin
would become too viscous
Benefits of filler particles
- Improves color stability
- Reduces H2O sorption
- Improves compressive and tensile strength
- Reduces coefficient of thermal expansion
- Reduces polymerization shrinkage
- Improves wear resistance
What is another name for a coupling agent in resin
silane
What is the role of coupling agent/silane
keeps everything together- it oats the filler particles to promote adhesion to the matrix