reactivity trends Flashcards

1
Q

what configuration do group 2 elements have and what charge ions do they make?

A

s^2 and they from 2+ cations

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2
Q

how do group 2 elements’ reactions with oxygen show their reactivities?

A

the redox reactions become more vigorous down the group

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3
Q

how do group 2’s reactions with water show reactivity?

A

more vigorous down group

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4
Q

what is formed between group 2 and oxygen?

A

white oxides

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5
Q

what is formed between group 2 and water?

A

metal hydroxide

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6
Q

what is formed between group 2 and acid?

A

salt

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7
Q

what observation and ph of MgO + water?

A

no observation 8-9

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8
Q

what observation and ph of CaO-BaO + water?

A

white oxide expands, producing a lot of steam. alkalinity increases down group

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9
Q

how does solubility change going down group 2 hydroxides?

A

increases because more OH- ions are released which makes it more alkaline

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10
Q

what uses of group 2 compounds are there?

A
  1. calcium hydroxide neutralises soil
  2. calcium carbonate treats indigestion
  3. milk of magnesia (magnesium hydroxide) is an antacid
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11
Q

how does calcium carbonate work as an antacid?

A

CaCO3 + 2HCl -> CaCl2 + H2O + CO2

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12
Q

what trend exists in BP in the halogens?

A

boiling point increases down group because the molecules increase - stronger dipole interactions

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13
Q

what reactivity trend exists in the halogens and why does it exist?

A

reactivity decreases down the group

this can be investigated by displacement reactions with other halides and noting colour

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14
Q

what is disproportionation?

A

oxidation and reduction of the same element such as
Cl2 + 2NaOH -> NaCl + NaOCL
Cl2 + H2O HClO + HCl

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15
Q

what are the benefits and worries of using chlorine in water treatment?

A

good: kills bacteria
bad: toxic an chlorinated hydrocarbons can be carcinogenic

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16
Q

what is the carbonate ion test?

A
  1. add dilute nitric acid to sample

2. pass gas through limewater

17
Q

what is the test for sulphate ions?

A
  1. barium nitrate solution

2. positive result is white precipitate of barium sulphate

18
Q

what is the test for ammonium ions?

A
  1. a NaOH to the sample and warm
  2. test gas with damp red litmus
  3. positive result is blue
19
Q

what is the correct order of tests?

A
  1. carbonate ions to prevent further contamination
  2. sulphate ions as they would come up in test 3
  3. halide