amount of substance Flashcards

1
Q

what is molar mass?

A

the mass in grams off 1 mole of a substance

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2
Q

what is the term ‘amount of substance’?

A

measured in moles

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3
Q

what is Avagadro’s constant?

A

6.02x10^23 atoms in a mole

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4
Q

what is molar gas volume?

A

one mole of a gaseous substance occupies 24 dm^-3

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5
Q

what is the empirical formula?

A

the simplest whole number ratio of atoms in an element

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6
Q

what is the molecular formula?

A

the number and type of atoms of each element in a molecule

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7
Q

what does anhydrous mean?

A

contains no water

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8
Q

what does hydrated mean?

A

contains water

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9
Q

what is ‘water of crystallisation’?

A

the water molecules in a hydrated salt

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10
Q

how do you calculate the formula of a hydrated salt via percentage/mass composition?

A

use the mass of water to find the simplest whole no. ratio

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11
Q

how do you calculate the formula of a hydrated salt via experimentation?

A
  1. weigh the empty crucible and then the hydrated salt
  2. heat the crucible
  3. reweigh
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12
Q

what are the problems with experimental formulae of hydrated salts?

A
  1. we assume all the water has been lost-should heat to a constant mass
  2. we assume there is no further decomposition
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13
Q

how do you find N in solution?

A

N=CV

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14
Q

what is a standard solution?

A

a solution of known concentration. made by dissolving an exact mass of solute in a solvent and making it up to an exact volume.

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15
Q

what is the ideal gas equation?

A

pV = nRT

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16
Q

what assumptions are made in the ideal gas equation?

A
  1. random motion
  2. elastic collision
  3. negligible size
  4. no intermolecular forces
17
Q

what do the letters in the real gas equation mean?

A
p = pressure (Pa)
V = volume (m^3)
n = moles (mol)
R = ideal gas constant 8.31 jmol^-1K^-1
T = temperature (K)
18
Q

what is stoichiometry?

A

the ratio of moles of each substance in a chemical equation

19
Q

why is 100% percentage yield so hard to achieve?

A
  1. the reaction may be reversible
  2. the reactants may contain impurities
  3. there may be by-products
  4. reactants/products may be left in the apparatus
  5. product lost during separation/filtration
20
Q

what is the % yield calculation?

A

actual yield/theoretical yield

21
Q

what is atom economy?

A

the proportion of products formed that are actually useful

22
Q

what is the calculation for atom economy?

A

molecular mass of desired product/Mr of all products

23
Q

why is a high atom economy beneficial for sustainability?

A
  1. makes better use of finite resources

2. reduces the need to process waste products