amount of substance Flashcards
what is molar mass?
the mass in grams off 1 mole of a substance
what is the term ‘amount of substance’?
measured in moles
what is Avagadro’s constant?
6.02x10^23 atoms in a mole
what is molar gas volume?
one mole of a gaseous substance occupies 24 dm^-3
what is the empirical formula?
the simplest whole number ratio of atoms in an element
what is the molecular formula?
the number and type of atoms of each element in a molecule
what does anhydrous mean?
contains no water
what does hydrated mean?
contains water
what is ‘water of crystallisation’?
the water molecules in a hydrated salt
how do you calculate the formula of a hydrated salt via percentage/mass composition?
use the mass of water to find the simplest whole no. ratio
how do you calculate the formula of a hydrated salt via experimentation?
- weigh the empty crucible and then the hydrated salt
- heat the crucible
- reweigh
what are the problems with experimental formulae of hydrated salts?
- we assume all the water has been lost-should heat to a constant mass
- we assume there is no further decomposition
how do you find N in solution?
N=CV
what is a standard solution?
a solution of known concentration. made by dissolving an exact mass of solute in a solvent and making it up to an exact volume.
what is the ideal gas equation?
pV = nRT
what assumptions are made in the ideal gas equation?
- random motion
- elastic collision
- negligible size
- no intermolecular forces
what do the letters in the real gas equation mean?
p = pressure (Pa) V = volume (m^3) n = moles (mol) R = ideal gas constant 8.31 jmol^-1K^-1 T = temperature (K)
what is stoichiometry?
the ratio of moles of each substance in a chemical equation
why is 100% percentage yield so hard to achieve?
- the reaction may be reversible
- the reactants may contain impurities
- there may be by-products
- reactants/products may be left in the apparatus
- product lost during separation/filtration
what is the % yield calculation?
actual yield/theoretical yield
what is atom economy?
the proportion of products formed that are actually useful
what is the calculation for atom economy?
molecular mass of desired product/Mr of all products
why is a high atom economy beneficial for sustainability?
- makes better use of finite resources
2. reduces the need to process waste products