Reactivity 1.4 (HL) Flashcards
Entropy (S)
Measure of the ways in which the available energy of a system can be distributed among the particles of a system (JK-1 mol-1)
Can entropy be measured?
Yes, absolute values can be measured
Why would entropy increase (4 ways)
- Mixing different states
- Increasing distance between particles (changing state)
- Increasing movement of particles (increasing temperature)
- Increasing the number of particles (mol ratio)
Entropy change formula
Differences between the total entropy of the products and the total entropy of the reactants (Sp - Sr)
Gibbs Energy Change (g)
Energy obtained from a chemical reaction that is available to do work (kj mol-1)
Value of G
Always negative as it is energy obtained
Gibbs energy change formula
G = H - T S
Spontaneous reaction
System becomes more stable (able to do work) Once started, it does not need any additional energy. G must be negative
Reaction Quotient (Q)
Ratio of products and reactants concentration when Q=0
Equilibrium constant (K)
Value of the reaction quotient in equlibrium.
When is K=0?
G is greater than 30kj mol-1
No reaction - impossible.
When is K smaller than 1?
G is between 0 and 30 kjmol1
Partial reaction occurs
When is K=1?
When G=0
Partial reaction occurs
When is K greater than 1?
G is greater than 0 and 30kjmol
Partial reaction occurs
When is K»1?
G is smaller than -30kjmol
Complete reaction occurs