Rates of Reaction Flashcards

1
Q

What is a Homogeneous Catalysis

A

A homogeneous catalysis is catalysis in which both reactants and the catalyst are in the same phase. I.e. there is no boundary between the reactants and the catalyst

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2
Q

What is a Heterogeneous Catalysis

A

A Heterogeneous catalysis is a catalysis in which the reactants and the catalyst are in different phases, i.e. there is a boundary between the reactants and the catalyst

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3
Q

What is Autocatalysis

A

Autocatalysis is catalysis in which one of the products of the reaction acts as a catalyst for the reaction.

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4
Q

What is the Rate of Reaction

A

The rate of reaction is the change in concentration per unit time of any one reactant or product.

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5
Q

What is the instantaneous rate of reaction

A

The instantaneous rate of reaction is the rate of reaction at any one particular time during the reaction

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6
Q

What is a catalyst

A

A catalyst is a substance that alters the rate of a chemical reaction but is not consumed in the reaction

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7
Q

What is an enzyme

A

An enzyme is a substance that is produced by a living cell and acts as a biological catalyst

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8
Q

What is an example of Autocatalysis

A

MnO4- + 8H+ +5Fe2+ -> Mn2+ +5Fe3+ + 4H20

Whereby Mn2+ is the catalyst

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9
Q

What is an example of a heterogeneous catalysis

A

Methanol oxidised to methanal using platinum as a catalyst

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10
Q

What is an example of an enzyme

A

Maltase In Maltose-> glucose

Amylase In Starch->sugars(maltose)

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11
Q

What is a catalyst called that slows down reactions and give an example

A

A negative catalyst/inhibitors

Example: Glycerine in Hydrogen Peroxide to slow down decomposition

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12
Q

What is an example of a Homogeneous Catalysis

A

The Iodine Snake/Elephant toothpaste

2H202 —KI—> 2H20 + 02

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13
Q

What is the Activation energy

A

The Activation energy is the minimum energy that colliding particles must have for a reaction to occur , i.e the minimum energy required for effective collisions between particles to occur.

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14
Q

What is a Reaction Profile Diagram

A

A Reaction profile Diagram is a graph which shows the change in energy of a chemical reaction with time as the reaction progress

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15
Q

What is a Catalytic

Convertor

A

A catalyst convertor is a device in the exhaust system of a motor vehicle which contains catalysts to convert pollutants in the exhaust gases to less harmful substances

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16
Q

What is a catalyst poison

A

A catalyst poison is a substance that makes a catalyst inactive

17
Q

What is an effective collision

A

It is one that results in the formation of products

18
Q

Is the energy of the reactants higher or lower than that of the products in an endothermic reaction?

A

Higher

19
Q

Is the energy of the reactants higher or lower than that of the products in an exothermic reaction?

A

Lower

20
Q

Describe a catalytic convertor

A

A catalytic convertor consists of a thin coating of metals platinum, palladium and rhodium on a ceramic or metal ‘honeycomb’ inside a stainless steel case

21
Q

what dangerous gases does a catalytic convertor take in

A

CO-Carbon Monoxide
NO-Nitrogen Monoxide
NO2-Nitrogen Dioxide
Hydrocarbons

22
Q

What gases does a catalytic convertor give out?

A

H20-Water
N2-Nitrogen gas
CO2-Carbon Dioxide

23
Q

Explain the surface Adsorption Theory

A
  1. Molecules diffuse towards the surface
  2. Vacant D-orbitals to Form temporary bonds with molecules
  3. The Higher concentration of the molecules makes it more likely for the molecules to collide(leading to more collisions, more effective collisions)
  4. Products form
  5. Desorption-products leave the surface
24
Q

List the 5 factors affecting the Rates of Reaction

A
  1. Nature of Reactants
  2. Particle Size
  3. Concentration
  4. Temperature
  5. Catalysts