Quiz (01.15.2021) Flashcards

1
Q

we define the ___ as the material or process within which we are studying the energy changes within

A

system

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

we define the ____ as everything else with which the system can exchange energy

A

surroundings

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

a ____ is the amount of energy needed to move 1kg mass a distance of 1 meter

A

joule (J)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

A _____ is the amount of energy needed to raise the temperature of one gram of water 1C

A

calorie (cal)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

kcal =

A

energy needed to raise 1000g of water 1C, Calories = kcal

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

____ is the study of energy and its interconversions

A

thermodynamics

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

the ___ energy is the sum of the kinetic and potential energies of all the particles that compose the system

A

internal

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

the change in the internal energy of a system only depends on…

A

the amount of energy in the system at the beginning and end

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

A ___ function is a mathematical function whose result only depends on the initial and final conditions not on the process used

A

state

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

when energy flows out of a system, change in energy in the system is ___

A

negative

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

when energy flows into the surroundings, change in energy in the surroundings is ___

A

positive

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

when energy flows into a system, change in energy in the system is ___

A

positive

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

when energy flows out of the surroundings, change in energy of the surroundings is ____

A

negative

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

energy is exchanged between the system and its surroundings through ___ and ___

A

heat; work

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

q and w are NOT state functions, their value depends on the process. change in energy =

A

q + w (heat plus work)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

the heat capacity of an object is proportional to the following:

A

the mass, the specific heat of the material

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

q =

A

mass (g) x specific heat capacity x temperature change (C)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

measure of a substance’s intrinsic ability to absorb heat

A

specific heat capacity - the amount of heat energy required to riase the temperature of one gram of a substance 1C

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

Units for specific heat capacity

A

J/gxC

20
Q

The ___ is the amount of heat energy required to raise the temperature of one mole of a substance 1C

A

molar heat capacity

21
Q

Pressure-volume work is work caused by …

A

a volume change against an external pressure

22
Q

when gases exchange, change in volume is positive, but the system is doing work on the surroundings, so work of the gas is ___

A

negative

23
Q

as long as the external pressure is kept constant, work of the gas equals…

A

external pressure x change in volume of the gas

24
Q

conversion factor for 1 atm x L to Joules

A

1 atm x L equals 101.3 J

25
Q

system gains thermal energy, q (heat) is ___

A

positive

26
Q

system loses thermal energy, q (heat) is ___

A

negative

27
Q

work done on the system, w (work) is ____

A

positive

28
Q

work done by the system, w (work) is ____

A

negative

29
Q

energy flows into the system, change in internal energy is____

A

positive

30
Q

energy flows out of the system, change in internal energy is ____

A

negative

31
Q

amount in joules (J) required to raise temperature of 1g of water by 1C

A

4.18

32
Q

amount in calories (cal) required to raise temperature of 1g of water by 1C

A

1.00

33
Q

amount in Calories (C) required to raise temperature of 1g of water by 1C

A

0.00100

34
Q

amount in kilowatt-hour (KWh) required to raise temperature of 1g of water by 1C

A

1.16 x 10^-6

35
Q

the ___ of a system is the sum of the internal energy of the system and the product of pressure and volume - it is a state function

A

enthalpy

36
Q

what is the equation for enthalpy?

A

H = E + PV

37
Q

the enthalpy change of a reaction is…

A

the heat evolved in a reaction at constant pressure

38
Q

change in enthalpy of the reaction

A

the heat of the reaction at constant pressure

39
Q

usually change in enthalpy and change in energy are similar in value; the difference is largest for reactions that produce or use…

A

large quantities of gas

40
Q

when change in enthalpy is negative…

A

heat is being released by the system

41
Q

when heat is being released by the system, it is an ____ reaction

A

exothermic

42
Q

when change in enthalpy is positive…

A

heat is being absorbed by the system

43
Q

when heat is being absorbed by the sysrem, it is called an _____ reaction

A

endothermic

44
Q

for an exothermic reaction, the surrounding’s temperature ___

A

rises

45
Q

the products of an exothermic reaction have ___ chemical potential energy than the reactants

A

less

46
Q

in an endothermic reaction, the surrounding’s temperature ____

A

drops

47
Q

Products in an endothermic reaction have ____ chemical potential energy than the reactants.

A

more