Quantifying atoms and compounds Flashcards

1
Q

Mass spectrometer

A

used to confirm the existence of isotopes

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2
Q

Percentage abundance using the spectrum

A

% abundance= peak height / total peak height x 100

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3
Q

Mass spectrum

A

Graph of the relative mass of isotopes, calibrated on the C12 scale, plotted against the percentage abundance

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4
Q

RAM calculation

A

E(RIM x %) / 100

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5
Q

Mole

A

unit for counting particles

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6
Q

n

A

amount in moles

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7
Q

Avogadro’s number

A

6.02 x 10^23

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8
Q

NA

A

Avogadro’s number

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9
Q

Relative Mr

A

Molar mass

Sum of the relative atomic masses of elements in the molecular formula

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10
Q

Mr

A

g mol ^-1

Mass of one mole of a particular element or compound

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11
Q

n=

A

m/Mr- amount

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12
Q

Stoichometry

A

n(unknown)= coefficient(unknown) / coefficient(known) x n(known)

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13
Q

Percentage composition of an element

A

Mr of that element x number of atoms of that element in compound/ Mr of compound x 100

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14
Q

Empirical formula

A

Shows the elements and simplest whole number ratio of atoms

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15
Q

Molecular formula

A

shows exact number of atoms of each element in a molecule

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16
Q

X (molecular formula)=

A

Mr(MF) / Mr(EF)

17
Q

Elemental analysis of an organic compound procedure

A
  1. Mass of organic compound recorded
  2. Complete combustion occurs through apparatus
  3. Sodium hydroxide solution absorbs carbon dioxide in organic compound. Mass of carbon dioxide equal to mass increase of sodium hydroxide (carbon dioxide absorber)
  4. Drying agents absorb water in organic compound. Mass of water is equal to mass increase of drying agents (water absorber)
18
Q

Elemental analysis to determine empirical formula

A
  1. Calculate mass of carbon from mass of carbon dioxide produced via stoichometry
  2. Calculate mass of hydrogen from mass of water produced
  3. Subtract mass of carbon plus hydrogen from original mass to find mass of oxygen
  4. Using masses of O, C and H, calculate empirical formula
19
Q

RAM

A

Weighted average of isotopic masses of atoms of an element compared to the standard C12 isotope

20
Q

n= (not mass)

A

N / NA

21
Q

N

A

number of particles-how many

22
Q

RIM

A

mass of an atom of an isotope compared to the mass of a carbon 12 atom

23
Q

Relative molecular mass

A

Mass of 1 molecule of a substance compared to the the mass of 1 atom of C12 taken as 12 exactly

24
Q

Molar mass

A

Mass, in grams, of 1 mole of a substance