Materials from molecules Flashcards

1
Q

Molecule

A

A discrete group of atoms of known formula, bonded together

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2
Q

Lattice

A

Atoms bonded together in a continuous 3D structure

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3
Q

Intramolecular forces

A

bonds between non metal atoms which form molecules

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4
Q

Intermolecular forces

A

Bonds between molecules

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5
Q

Localised electrons

A

Shared electrons in a covalent bond which are found between the nuclei

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6
Q

VSEPR theory

A

Valence shell electron pair repulsion theory
Negatively charged electron pairs in the outer shell of an atom repel each other and are therefore placed as far away from each other as possible

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7
Q

Intermolecular forces strength

A

weaker than strong forms of bonding such as ionic, metallic and covalent bonds

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8
Q

when a substance is melted/vaporised

A

weak intermolecular forces are broken

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9
Q

Non polarised covalent bond

A

Equal distribution of valence electrons

no charge on either side of the bond (no net dipole)

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10
Q

Polarised covalent bond

A

Electrons will stay closer to the most electronegative atom which has a stronger pull on the electrons in the bond
created two oppositely charged poles- partial positive charge, partial negative charge

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11
Q

Level of polarity

A

Depends on the difference between the electronegativities

greater the difference, greater the polarity of the molecule

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12
Q

Non-polar molecules

A

Partial charges are evenly distributed around the molecule
Individual dipoles of the covalent bonds cancel each other out perfectly
no overall dipole

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13
Q

Polar molecules

A

Partial charges are unevenly distributed around the molecule

results in a net dipole

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14
Q

Strength order of intermolecular forces

A

H-bonding
Dipole-dipole
dispersion

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15
Q

Dipole-dipole

A

polar molecules
Attraction between the partial negative/positive ends of the polar molecules
more polar a molecule is, stronger the dipole-dipole forces

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16
Q

H-bonding

A

occurs in molecules where a hydrogen atom is covalently bonded to a FON atom
partial positive charge of hydrogen is attracted to lone pairs of electrons in FON atoms of neighbouring molecules

17
Q

Dispersion forces

A

Caused by temporary dipoles
result of random movement of electrons surrounding molecules which cause instantaneous dipoles
always present between molecules
Strength increases as Mr of molecule increases. Larger molecules have a larger number of electrons.
In larger molecules, dispersion forces can dominate over dipole-dipole forces

18
Q

Non metal properties

A

Soft
Low MP and BP
Don’t conduct electricity in molten or solid state

19
Q

Non metals soft

A

Intermolecular forces are weak

Bonds can be readily broken and substance is easily crushed or moulded

20
Q

Non metals low MP and BP

A

weak forces of attraction between particles

21
Q

Non metals dont conduct electricity

A

no free moving charged particles in either state