Metals Flashcards
Way in which metal is used
determined by its physical and chemical properties
Metals can be modified in 3 ways
Alloy production
Heat treatment
Coating
Alloys
Metals are mixed with small amounts of another substance, usually a metal ot carbon
The substances used are melted, mixed and then allowed to cool, creating an alloy
not a substance
Properties of alloys
Harder, less malleable and melt at low temps
- because atoms of diff. sizes do not pack in the same way as main metal and don’t allow the lattice to shift and bend. disruption of regular metallic lattice accounts for low melting point
Poor electrical conductors
-delocalised electrons have restricted movement due to close packing of different sized particles
Substitutional alloy
made up of elements with similar chemical properties and atoms of similar size to main metal
metal cations are attracted to sea of delocalised electrons so lattice is strongly bonded
Interstitial alloy
An alloy in which a small proportion of an element with atoms of small atomic radius is added to a metal.
Crystals of metal
region in a solid where particles are arranged in a regular way
continuous regular arrangement of cations surrounded by delocalised electrons
malleability and brittleness depend on size and arrangement of crystals
generally, smaller crystals result in a harder, more brittle metal (less free movement of layers of cation over each other)
Heat treatment
When metals are heated above a critical temperature, individual crystals merge.
when the metal is allowed to cool, the crystals reform
rate of cooling determines how large the new crystal will be
Quenching
Faster cooling
leads to smaller crystals
Annealing
allows more time for crystals to grow larger
Metallic nano materials
metal atoms arranged to make nano sized structures
particles, rods, wires
Properties metallic nano materials
different to bulk sample of same metal
because they have a high sa:v ratio compared to bulk size of similar volume
When size of metal crystal decrease, they have too few electrons to amount to a sea of delocalised electrons. Thus, they have different
-optical properties, electrical conductivity, thermal conductivity, metallic lustre