Qualitative Tests for Alkaloids Flashcards

1
Q

Reagent of Wagner’s/Bouchardat’s

A

Iodine in KI

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2
Q

Reagent of Valser’s

A

Mercuric Iodide

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3
Q

Reagent of Mayer’s

A

HgCl2 in KI

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4
Q

Reagent of Dragendorff’s

A

Potassium bismuth iodide

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5
Q

Reagent of Marme’s

A

Potassium cadmium iodide

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6
Q

Reagent of Hager’s

A

Saturated picric acid

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7
Q

Reagent of Scheibler’s

A

Phosphotungstic acid

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8
Q

Reagent of Sonnenschein’s

A

Phosphomolybdic acid

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9
Q

Result of Wagner’s/Bouchardat’s

A

Reddish brown ppt

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10
Q

Result of Valser’s

A

White ppt

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11
Q

Result of Mayer’s

A

White/cream ppt

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12
Q

Result of Dragendorff’s

A

Orange ppt

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13
Q

Result of Marme’s

A

Precipitation

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14
Q

Result of Hager’s

A

Precipitation

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15
Q

Result of Scheibler’s

A

Precipitation

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16
Q

Result of Sonnenschein’s

A

Precipitation

17
Q

For Codeine

A

Marquis
Hasemann

18
Q

For Atropine

A

Vitali-Morin
Gulielmo
Gerard’s

19
Q

For Quinine

A

Thalleioquin

20
Q

For Strychnine

21
Q

For Caffeine

22
Q

Reagent of Marquis

A

Formaldehyde
Conc. sulfuric acid

23
Q

Reagent of Hasemann

A

Ferric chloride

24
Q

Reagent of Vitali-Morin

A

Nitric acid

25
Reagent of Gulielmo
Sulfuric acid
26
Reagent of Gerard’s
Ethanol Mercuric chloride
27
Reagent of Thalleioquin
Acetic acid Ammonia Chlorine water
28
Reagent of Mandelin
Ammonium metavanadate Conc. sulfuric acid
29
Reagent of Murexide
Hydrochloric acid Potassium chlorate
30
Result of Marquis
Blue
31
Result of Hasemann
Blood red
32
Result of Vitali-Morin
Gray ppt
33
Result of Gulielmo
Red with flower odor
34
Result of Gerard’s
Yellow
35
Result of Thalleioquin
Fine blue fluorescence Green ppt with ammonia
36
Result of Mandelin
Violet
37
Result of Murexide
Purple or pink on paper chromatography