Properties of Period 3 Elements Flashcards

1
Q

Give the equation for the reaction of sodium with water

A

2Na(s) + 2H2O(l) –> 2NaOH(aq) + H2(g)

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2
Q

Give the equation for Magnesium with water

A

Mg(s) + 2H2O(l) –> Mg(OH)2(aq) + H2(g)

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3
Q

Give the equation for Magnesium with steam

A

Mg(s) + H2O(g) –> MgO(s) + H2(g)

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4
Q

Give the equation for chlorine forming HClO

A

Cl2(g) + H2O(l) –> HClO(aq) + HCl(aq)

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5
Q

Give the equation for chlorine forming HCl

A

2Cl2(g) + 2H2O(l) –> 4HCl(aq) + O2(g)

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6
Q

Give the equation for sodium with oxygen

A

2Na(s) + 1/2O2(g) –> Na2O(s)

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7
Q

Give the equation for magnesium with oxygen

A

2Mg(s) + O2(g) –> 2MgO(s)

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8
Q

Give the equation for aluminium with oxygen

A

4Al(s) + 3O2(g) –> 2Al2O3(s)

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9
Q

Give the equation for silicon with oxygen

A

Si(s) + O2(g) –> SiO2(s)

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10
Q

Give the equation for phosphorus with oxygen

A

P4(s) + 5O2(g) –> P4O10(s)

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11
Q

Give the equation for sulfur with oxygen

A

S(s) + O2(g) –> SO2(s)

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12
Q

Why does MgO have the highest melting point of all P3 oxides?

A
  • MgO has ionic bonds
  • strong electrostatic attraction between oppositely charged ions
  • these require alot of energy to overcome
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13
Q

Why does Al2O3 have more covalent character that MgO?

A
  • the Al3+ ion is smaller than the Mg2+ ion
  • meaning the Al3+ ions is more polarising than the Mg2+ ion
  • distorting the electron cloud around O2- ion more.
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14
Q

Give the equation for sodium oxide with water

A

Na2O(s) + H2O(l) –> 2Na+(aq) + 2OH-(aq)

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15
Q

Give the equation of magnesium oxide with water

A

MgO(s) + H2O(l) –> Mg(OH)2(aq)

🔑 point - magnesium hydroxide is only sparingly soluble so is only weakly alkaline.

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16
Q

What are the 2 insoluble oxides

A

Aluminium Oxide and Silicon dioxide so no reaction occurs.

17
Q

What is the PH when aluminium oxide and silicon dioxide are added to water.

A

7
There is no reaction to make the water acidic or alkaline

18
Q

What is the equation for phosphoric acid with water

A

P4O10(s) + 6H2O(l) –> 4H3PO4(aq)

19
Q

What is the equation for sulfur dioxide in water

A

SO2(g) + H2O(l) –> H2SO3(aq)
*Sulfurus acid

20
Q

What is the equation for sulfur trioxide with water

A

SO3(g) + H2O(l) –> H2SO4(aq)

21
Q

Give the equation for sodium oxide with H2SO4

A

Na2O(s) + H2SO4(aq) –> Na2SO4(aq) + H2O(l)

22
Q

Give the equation for magnesium oxide with HCl

A

MgO(s) + 2HCl(aq) –> MgCl2(aq) + H2O(l)

23
Q

What is it meant by amphoteric?

A

It can act as an acid or base

24
Q

Give an example of an amphoteric oxide

A

Aluminium oxide

25
Q

Give the equation for aluminium oxide when it acts as a base

A

Al2O3(s) + 6HCl(aq) –> 2AlCl3(aq) + 3H2O(l)

26
Q

Give the equation for aluminium oxide when it acts as a base

A

Al2O3(s) + 2NaOH(aq) + 3H2O(l) –> 2NaAl(OH)4(aq)

27
Q

Give the equation for phosphoric acid with sodium hydroxide

A

H3PO4(aq) + 3NaOH(aq) –> Na3PO4(aq) + 3H2O(l)

28
Q

Give the ionic equation for the reaction of phosphorus(V) oxide with an excess of sodium hydroxide solution

A

P4O10 + 12OH- –> 4PO43- + 6H2O

29
Q

Give the equation for sulfur dioxide in solution

A

SO2(aq) + 2NaOH(aq) –> Na2SO3(aq) + H2O(l)

30
Q

Give the equation for phosphoric oxide with sodium oxide

A

P4O10 + 6Na2O –> 4Na3PO4(aq)

31
Q

Give the equation for phosphoric oxide with magnesium oxide

A

P4O10 + 6MgO –> 2Mg3(PO4)2(aq)

32
Q

Explain using an equation why silicon oxide is classified as an acidic oxide

A

SiO2 + 2NaOH –> Na2SiO3 + H2O