Alcohols (P2+P3) Flashcards

1
Q

Name the mechanism, reagents and conditions from alkene to alcohol.

A

Direct hydration
reagents: steam
conditions and catalyst: conc H3PO4

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2
Q

2 advantages of hydration of ethene

A

high rate of reaction
high purity product made

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3
Q

2 disadvantages of hydration of ethene

A

high temp and pressure needed; increased cost
crude oil is non renewable

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4
Q

2 advantages of fermentation

A

uses renewable resources
low cost

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5
Q

2 disadvantages of fermentation

A

slow rate of reaction
less efficient

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6
Q

What is biofuel?

A

a fuel produced from biomass (renewable plant material)

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7
Q

2 advantages of biofuel

A

carbon neutral
comes from renewable raw materials

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8
Q

2 disadvantages of biofuel

A

food prices rise as crops used for biofuels
the supply of biofuels is dependent on crop harvest so is less reliable.

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9
Q

Name of mechanism, reagents and conditions from alcohols to alkenes.

A

elimination (dehydration)
reagent: H2SO4
conditions: hot, conc

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10
Q

Oxidation of primary alcohol under distillation forms an…
under what reagent and conditions
observation?

A

Aldehyde
reagent: acidified potassium dichromate
conditions: distillation
observation: orange to green

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11
Q

Ehanol oxidised to ethanal equation

A

CH3CH2OH + [O] –> CH3CHO +H2O

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12
Q

Oxidation of primary alcohol under reflux forms a…
under what reagent and conditions
observation?

A

Carboxylic acid
reagent: acidified potassium dichromate
conditions: reflux
observation: orange to green

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13
Q

Ethanol oxidised to ethanoic acid equation

A

CH3CH2OH + 2[O] –> CH3COOH +H2O

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14
Q

Ethanal oxidised into ethanoic acid equation

A

CH3CHO + [O] –> CH3COOH
NO WATER MADE

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15
Q

Why is reflux used to oxidise an alcohol into a carboxylic acid?

A

reflux doesn’t allow any reactant vapour to escape.

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16
Q

Oxidation of secondary alcohol forms a…
under what regent and conditions
observation?

A

Ketone
reagent: acidified potassium dichromate
conditions: distillation or reflux
observation: orange to green

17
Q

Propan-2-ol oxidised to propanone equation

A

CH3CH(OH)CH3 + [O] –> CH3COCH3 + H2O

18
Q

Test for aldehydes or ketones (silver mirror)

A

Tollens reagent
warm gently
Aldehyde: Silver mirror forms
Ketone: NVC

19
Q

Test for aldehydes and ketones (Fehling’s test)

A

Fehling’s solution
warm gently
Aldehyde: blue to brick red ppt
Ketone: NVC

20
Q

Test for carboxylic acid

A

Sodium carbonate
effervescence