Plastic restorations - resin modified glass Ionomer cements Flashcards
What type of reaction is the polymerisation component?
light activated free-radical methacrylate reaction
What is the maximum depth of the cement which can be light cured (polymerisation)?
0.5mm
Why is the max depth of light curing for the polymerisation reaction 0.5mm?
limited light transmission through these material
What is a tri-cured glass ionomer resin?
material can be light cured and chemically cured
a second chemical initiator system has been incorporated into some RMGIC products to compensate for the limited light-cure polymerisation reaction
to set the resin
What are the 2 types of reactions in order to set the resin part?
polymerisation reaction - free radical methacrylate reaction effected by light activation
- light
+ redox reaction
- chemical
How any stages are in the dual-cured RMGIC reaction?
4
What are the 4 clinical stages of the dual-cured RMGIC reaction?
- commences when powder and liquid mixed together
- light activation of polymerisation reaction
- light activation stopped
- restoration complete
What are the 4 sages of the dual-cured RMGIC setting reaction?
What are the stages of the tri-cured RMGIC setting reaction?
Do the acid-base and polymerisation setting reactions need to be initiated at the same time?
yes
Why do the acid-base and polymerisation setting reactions need to be initiated at the same time?
as the material wont fully set at the same time
Why is does the acid-base and polymerisation reactions rarely start at the same time?
as the addition of HEMA retards the setting rate of the acid-base reaction
Why does shrinkage occur?
polymerisation phase
What kind of setting reaction occurs when HEMA polymerises?
exothermic
What are the 2 mechanisms for bonding to the tooth?
calcium chelation
subsidiary collagen bonding
What are factors limiting the success of the adhesive bond?
What can cause excessive expansion?
affinity for polyHEMA for water can cause excess expansion if not mixed correctly (i.e too much monomer)
What happens as the polyEMA absorbs water?
mechanical properties begin to fall
What is the fluoride release like?
sustained release
When is the most fluoride released form the cement?
first 10-15 days
What allows fluoride release long-term?
slow setting of glass ionomer phase of the cement
polyHEMA matrix provides n easier pathway for the ionic species to migrate through the cement
HEMA is hydrophilic
What is occurring as fluoride is released?
the restoration is degrading
is R,GIC prone to staining?
yes, intrinsic staining
When should a tri-cure system be used?
where the material cannot be fully light cured