Plastic restorations - Resin modified glass ionomer cements Flashcards

1
Q

What is a resin modified glass ionomer?

A

it is close to a glass ionomer but has some resin it

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2
Q

What are the 2 hybrid materials?

A

compomer and resin modified glass ionomer

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3
Q

What are the advantages of resin based composites?

A

command set by visible light

better wear resistance

lower solubility

early compressive and flexural strength

good polishability

ability to retain its polish

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4
Q

What are the disadvantages of glass ionomer cements?

A

lower early strength

susceptibility to erosion

slower setting phase

risk detection

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5
Q

is resin hydrophobic or hydrophilic?

A

hydrophobic effectively

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6
Q

What are the constituents of RMGICS? (BASIC)

A

Are conventional glass ionomer cements and water-soluble resin and modified poly(acrylic acids)

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7
Q

What are olyacrylic acids?

A

they have pendant methacrylate groups or methacryloxy groups grafted onto the polyacid chain (copolymers)

= copolymers

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8
Q

What is the resin group?

A

usually HEMA

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9
Q

What is the glass ionomer part?

A

polyacid

tartaric acid

water

ion leachable glass

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10
Q

What is the resin part?

A

water soluble (miscible) monomer

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11
Q

What us HEMA?

A

SMALL HIGHLY REACTOVE MONOMER MOLECULE

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12
Q

Is glass ionomer hydrophobic or hydrophilic?

A

hydrophilic

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13
Q

What connects the hydrophobic resin composite and hydrophilic GI?

A

HEMA

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14
Q

What is the problem with HEMA?

A

it is a powerful dermatological sensitizer causing chemical dermatitis

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15
Q

What form is HEMA a hazard?

A

in the unset form, after polymerisation it is fine

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16
Q

What will happen f the level of HEMA polymerisation is low?

A

then unconverted monomer can leach out as polyHEMA which absorbs water very quickly

17
Q

What is the effect of freed HEMA monomer?

A

move into surrounding dental hard and surrounding tissues

may potentially have toxological effects on the dental pulp and osteoblasts if polymer degrades

18
Q

How does RMGIC decrease microleakage?

A

it seals the dentinal tubules opened during cavity preparation and decreases the risk of microleakage

decrease microcontamination

19
Q

What are the constituents of RMGIC? (powder)

A

Barium, strontium or aluminosilicate glass

vacuum-dried polyacrylic acid

potassium persulphate

ascorbic acid

pigments

20
Q

Why use barium, strontium or aluminosilicate glass? (powder)

A

improved strength

imparts radiopacity

21
Q

What reaction makes the poly salt matrix? (powder)

A

vacuum-dried polyacrylic acid and glass

22
Q

What provides the chemical cure (powder)

A

potassium persulphate

ascorbic acid

23
Q

What are the chemical constituents? (liquid)

24
Q

What does polyacrylic acid react with (liquid)?

A

reacts with the glass to form the poly salt matrix

25
What does the copolymer do (liquid)?
ability to undergo both acid-base and polymerisation reactions helps form interpenetrating network (the set)
26
What is the polymerisation reaction due to?
resin
27
What is the acid-base reaction due to?
Glass ionomer
28
What sharpens the acid-base reaction set? (liquid)
tartaric acid
29
What is the role of water in RMGIC? (LIQUID)
permits reaction between the polyacid and the glass
30
What happens to translucency as particle size is reduced?
as particle size is reduced there is a progressive loss in translucency (gets more opaque)
31
What reaction does the water-miscible monomer permit?
polymerisation reaction
32
What else happens during the polymerised resin phase?
it forms a scaffolding while the ionomer cement matrix is being formed
33
What happens as the resin content is increased?
the acid-base reaction is slowed as the resin matrix decreases the motility of the other ions to form the chemical reaction
34
When is the effect of the resin addition primarily seen?
during the initial stages of the set when the glass ionomer cement is weakest
35
Why does the resin need to be soluble in water?
as the cement remains water based
36
What happens if there is an absence of water?
there is no reaction between the polyacid and the glass
37
Why is there a limit in the number of resin systems used in the material?
due to its hydrophobicity
38
What 2 types of setting reaction stake place in the material?
acid-base polymerisation