Dental Amalgam Flashcards

1
Q

What is amalgam?

A

alloy + mercurary

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2
Q

What is dental amalgam?

A

alloy containing silver, tin and certain elements and mercury

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3
Q

What is the reaction of alloy and mercury called?

A

amalgamation

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4
Q

What is the predominant element in alloy?

A

silver

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5
Q

What does silver combine with?

A

tin, the main reaction

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6
Q

Why is mercury added?

A

increase rate of reaction - pre-amalgamation

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7
Q

What does zinc preferentially react with?

A

oxygen

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8
Q

What would you call an alloy with less than 0.01% zinc?

A

zinc free alloys

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9
Q

What percent are zinc containing alloys?

A

more than or equal to 0.01%

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10
Q

When does zinc produce hydrogen gas?

A

when reacted with water

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11
Q

Why is moisture control important (specifically with zinc)?

A

zinc reacts with water to produce hydrogen gas and excessive delayed expansion

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12
Q

Do the majority of alloys have zinc?

A

no

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13
Q

What form of mercury is used and why?

A

pure form otherwise inferior physical properties result

adversely affect the setting characteristics of the amalgam

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14
Q

Is mercury distilled?

A

yes, 3 times

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15
Q

What is the appearance of contaminated mercury?

A

dull appreance - we know encapsulate

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16
Q

What are the 3 phases of amalgamation? (mercury with alloy)

A
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17
Q

What is the unreacted core surrounded by?

A

amalgam matrix

(gamma 1 silver/mercury and gamma 2 tin/mercury)

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18
Q

What depth of the outer layer react with alloy particles?

A

3-5 um

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19
Q

What is gamma 1?

20
Q

What is the gamma 2 phase?

A

tin-mercury phase

21
Q

What is the most critical phase?

A

gamma 2 phase

22
Q

What are the features of the gamma 2 phase?

A

most chemically electrically active component

physical properties inferior to gamma and gamma 1 phases

more prone to corrosion

poor tensile strength

23
Q

What phases are the green, purple and blue in the amalgam?

A

green = gamma 1 (silver/mercury)
purple = gamma 2 (tin/mercury)
blue = gamma (silver/tin)

24
Q

What is tensile strength?

A

ability of a material to withstand pulling forces in an axial direction

25
What shape do you test tensile strength on?
cylinder
26
What is creep?
gradual dimensional change under load
27
What phase is more susceptible to creep?
gamma 2
28
What can creep lead to?
ditching
29
What is ditching?
the amalgam has move over time, thinned out at the margin - can chip creates channels called a ditch
30
What is the percent of creep with amalgam?
c6%
31
What does high copper amalgams attempt to eliminate?
gamma 2 phase
32
What percent is high copper amalgams?
above 13% content
33
What is the result of high copper amalgams?
higher mechanical strength properties more rapid set to full strength reduction in creep reduced susceptibility to corrosion
34
What is compressive strength?
ability of a material to withstand axially loaded pushing forces (applied along long axis)
35
What are the setting reactions of high copper dental amalgam?
essentially the same as conventional alloys
36
In high copper amalgam setting reactions, what phase has little to nothing left in the final amalgam?
gamma 2
37
In high copper amalgam, what 2 thing preferentially react?
copper and tin
38
What complex is formed in the high copper amalgam setting reaction?
silver-tin-copper complex little to no gamma 2 left
39
In high copper amalgam, hat surrounds the silver/tin/copper complex?
copper/tin
40
What are the types of high copper amalgam alloy?
dispersed phase ternary alloys
41
Describe the dispersed phase of high copper amalgam alloy?
copper dispersed throughout the alloy alloy particles either contain silver-tin or silver-copper silver content may be kept the same as conventional alloys increased strength
42
Describe ternary alloys (high copper content amalgam alloy)
contain 3 elements usually silver, tin and copper all in one particle compositional
43
What is the effect of eliminating gamma 2 in high copper alloys?
greater microleakage increased postoperative sensitivity increased risk of recurrent caries may be overcome by bonding in situ
44
What is the role of gamma 2 in amalgam?
corrosion product of gamma2 fill the marginal micro gap at cavity interface decrease microleakage
45
What are the 3 types of alloy?
lathe cut spherical admixed
46
What is the lathe cut alloy like?
irregular particles produced - affects reactivity with mercury blend various particle sizes to reduce reactivity
47
What is admixed alloys like?
combination of irregular and spherical particles sometimes called blended