Dental Amalgam Flashcards
What is amalgam?
alloy + mercurary
What is dental amalgam?
alloy containing silver, tin and certain elements and mercury
What is the reaction of alloy and mercury called?
amalgamation
What is the predominant element in alloy?
silver
What does silver combine with?
tin, the main reaction
Why is mercury added?
increase rate of reaction - pre-amalgamation
What does zinc preferentially react with?
oxygen
What would you call an alloy with less than 0.01% zinc?
zinc free alloys
What percent are zinc containing alloys?
more than or equal to 0.01%
When does zinc produce hydrogen gas?
when reacted with water
Why is moisture control important (specifically with zinc)?
zinc reacts with water to produce hydrogen gas and excessive delayed expansion
Do the majority of alloys have zinc?
no
What form of mercury is used and why?
pure form otherwise inferior physical properties result
adversely affect the setting characteristics of the amalgam
Is mercury distilled?
yes, 3 times
What is the appearance of contaminated mercury?
dull appreance - we know encapsulate
What are the 3 phases of amalgamation? (mercury with alloy)
What is the unreacted core surrounded by?
amalgam matrix
(gamma 1 silver/mercury and gamma 2 tin/mercury)
What depth of the outer layer react with alloy particles?
3-5 um
What is gamma 1?
silver
What is the gamma 2 phase?
tin-mercury phase
What is the most critical phase?
gamma 2 phase
What are the features of the gamma 2 phase?
most chemically electrically active component
physical properties inferior to gamma and gamma 1 phases
more prone to corrosion
poor tensile strength
What phases are the green, purple and blue in the amalgam?
green = gamma 1 (silver/mercury)
purple = gamma 2 (tin/mercury)
blue = gamma (silver/tin)
What is tensile strength?
ability of a material to withstand pulling forces in an axial direction
What shape do you test tensile strength on?
cylinder
What is creep?
gradual dimensional change under load
What phase is more susceptible to creep?
gamma 2
What can creep lead to?
ditching
What is ditching?
the amalgam has move over time, thinned out at the margin - can chip
creates channels called a ditch
What is the percent of creep with amalgam?
c6%
What does high copper amalgams attempt to eliminate?
gamma 2 phase
What percent is high copper amalgams?
above 13% content
What is the result of high copper amalgams?
higher mechanical strength properties
more rapid set to full strength
reduction in creep
reduced susceptibility to corrosion
What is compressive strength?
ability of a material to withstand axially loaded pushing forces (applied along long axis)
What are the setting reactions of high copper dental amalgam?
essentially the same as conventional alloys
In high copper amalgam setting reactions, what phase has little to nothing left in the final amalgam?
gamma 2
In high copper amalgam, what 2 thing preferentially react?
copper and tin
What complex is formed in the high copper amalgam setting reaction?
silver-tin-copper complex
little to no gamma 2 left
In high copper amalgam, hat surrounds the silver/tin/copper complex?
copper/tin
What are the types of high copper amalgam alloy?
dispersed phase
ternary alloys
Describe the dispersed phase of high copper amalgam alloy?
copper dispersed throughout the alloy
alloy particles either contain silver-tin or silver-copper
silver content may be kept the same as conventional alloys
increased strength
Describe ternary alloys (high copper content amalgam alloy)
contain 3 elements usually silver, tin and copper all in one particle
compositional
What is the effect of eliminating gamma 2 in high copper alloys?
greater microleakage
increased postoperative sensitivity
increased risk of recurrent caries
may be overcome by bonding in situ
What is the role of gamma 2 in amalgam?
corrosion product of gamma2 fill the marginal micro gap at cavity interface
decrease microleakage
What are the 3 types of alloy?
lathe cut
spherical
admixed
What is the lathe cut alloy like?
irregular particles produced - affects reactivity with mercury
blend various particle sizes to reduce reactivity
What is admixed alloys like?
combination of irregular and spherical particles
sometimes called blended