Physical Chemistry Flashcards

1
Q

A branch of chemistry that deals with the study of the structures and physical properties of matter with the laws of chemical interaction and the theories governing these interaction

A

Physical chemistry

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2
Q

Involve the kinetic theory of gases and its application to solution and Debye-Heckel theory of electrolytes

A

Newtonian Mechanics and Electrostatics

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3
Q

Involved motion of individual molecules and individual electronic, spin, vibrational, and rotational energy transitions

A

Microscopic

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4
Q

Involves measurement of properties of matter as a bulk such as pressure, temperature, volume and absorbance

A

Macroscopic

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5
Q

It results from a mic true of neutral atoms, free electrons and charged ions usually s fluid but due to charged particles present, it responds to and generates electromagnetic forces

A

Plasma

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6
Q

Special state of matter in which atoms in a confined gas act together like a single giant particle after being cooked cryogenically to a temperature near absolute zero

A

Bose-Einstein Condensate

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7
Q

Refers to the physical state of gas specified in terms of its physical properties like volume, pressure, temperature and number of moles

A

State of a system

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8
Q

In the kinetic molecular theory, gases are considered to be composed of minute discrete particles called

A

Molecules

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9
Q

The molecules within a container are believed to be ceaseless chaotic motion during which they collide with each other and with the walls of the container

A

Kinetic molecular theory

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10
Q

Inasmuch as the pressure of a gas within a container does not vary with time at any given temperature and pressure, the molecular collision must involved no energy loss due to fiction.

A

Kinetic molecular theory

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11
Q

In the kinetic molecular theory, all molecular collisions are considered to be perfectly

A

Elastic

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12
Q

The absolute temperature is s quantity proportional to the average kinetic energy of all molecules in a system

A

Kinetic molecular theory

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13
Q

At relatively low pressures, the average distances between molecules are large compared with molecular diameters and hence the attractive forces between molecules may be considered negligible

A

Kinetic molecular theory

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14
Q

The vapor density method of the determination of molecular weight is developed by

A

Jean Baptiste Andre Dumas

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15
Q

The regnant method of the determination of molecular weight is developed by

A

Henry victor Renault

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16
Q

As soon as equilibrium is established between the liquid and vapor,mother pressure exerted by the vapor is known as the

A

Saturated vapor pressure

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17
Q

When the critical point is reached, there is or no distinction between the liquid and the vapor

A

No

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18
Q

The resistance offered by the fluid to the flow of another fluid

A

Viscosity

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19
Q

It is produced by the shearing effect of moving one layer of the fluid past another

A

Viscosity

20
Q

Viscosity increases with increasing temperature when it come to

A

Gases

21
Q

The pouiseuille equation is also known as

A

Ostwald viscosimeter

22
Q

This law if applicable with the radius of the falling body is greater than the distance between the molecules of the liquid

A

Stokes law

23
Q

The du Nouy Ring Method uses a device called

A

Tension enter

24
Q

The tensiometer was developed in

A

Rockefeller institute for medical research

25
Q

Constituent structural units are arranged in a definite geometrical configuration characteristic of a substance. It melts sharply at constant and definite temperature

A

Crystalline

26
Q

Solids which does not show definite configurational arrangement and are not considered as true solids but highly supercooled liquids with very high viscosity. It melts gradually over a temperature interval

A

Amosphous

27
Q

The amount of heat evolved during crystallization or solidification per mile of substance at a given temperature and pressure

A

Heat of crystallization

28
Q

The reverse of heat of crystallization which is the amount of heat that must be absorbed in the transition of one mole of solid to liquid

A

Heat of fusion

29
Q

A study dealing with the geometry, properties and structure of crystals and crystalline substances

A

Crystallography

30
Q

In a crystal system, there may be — crystal forms

A

230

31
Q

Crystal systems may be groups into — classes according to symmetry

A

32

32
Q

Existence of substanc s in more than one modification

A

Polymorphism

33
Q

Polymorphism occurring in elements

A

Allotropy

34
Q

The transformation from one form to another takes place at a temperature known as transition temperature of transition point

A

Allotropy

35
Q

It produces electricity as a result of spontaneous reactions occurring inside it where the cathode has a higher potential than the anode

A

Galvanic cell

36
Q

Non-spontaneous reaction is driven by an external source of current. They have a common electrolyte and no salt bridge

A

Electrolytic cell

37
Q

Reduction occurs in the — and oxidation occurs in the —

A

Cathode

Anode

38
Q

In electrolytic cells, the anode and cathode is

A

+

-

39
Q

In galvanic cells, the anode and cathode is

A

-

+

40
Q

A reduction brought about by the passage of a direct current through a solution of an electrolyte

A

Electrolysis

41
Q

The phenomena that occurs in electrolytic conduction

A

Mass movement of ions

Occurring of Oxidation-Reduction Reaction

42
Q

The mass of a substance involved in the reaction at the electrode is proportional to the quality of electricity passed though the solution

A

Faraday’s Law

43
Q

Governs the temperature dependence of pressure in a two-phase, one component system

A

Chaperoning equation

44
Q

Gives the r lotion ship between pressure and temperature for a two-phase, one-component system assuming that the vapor phase is ideal and the molar volume of the condensed phase is negligible compared to that of the vapor phase

A

Clausius-Clapeyron Equation

45
Q

Solutions with heat of mixing equal to zero and the volume of the solution is the sum of the volumes of the components of the solution

A

Ideal solution