Physical Chemistry Flashcards

1
Q

A branch of chemistry that deals with the study of the structures and physical properties of matter with the laws of chemical interaction and the theories governing these interaction

A

Physical chemistry

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2
Q

Involve the kinetic theory of gases and its application to solution and Debye-Heckel theory of electrolytes

A

Newtonian Mechanics and Electrostatics

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3
Q

Involved motion of individual molecules and individual electronic, spin, vibrational, and rotational energy transitions

A

Microscopic

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4
Q

Involves measurement of properties of matter as a bulk such as pressure, temperature, volume and absorbance

A

Macroscopic

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5
Q

It results from a mic true of neutral atoms, free electrons and charged ions usually s fluid but due to charged particles present, it responds to and generates electromagnetic forces

A

Plasma

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6
Q

Special state of matter in which atoms in a confined gas act together like a single giant particle after being cooked cryogenically to a temperature near absolute zero

A

Bose-Einstein Condensate

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7
Q

Refers to the physical state of gas specified in terms of its physical properties like volume, pressure, temperature and number of moles

A

State of a system

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8
Q

In the kinetic molecular theory, gases are considered to be composed of minute discrete particles called

A

Molecules

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9
Q

The molecules within a container are believed to be ceaseless chaotic motion during which they collide with each other and with the walls of the container

A

Kinetic molecular theory

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10
Q

Inasmuch as the pressure of a gas within a container does not vary with time at any given temperature and pressure, the molecular collision must involved no energy loss due to fiction.

A

Kinetic molecular theory

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11
Q

In the kinetic molecular theory, all molecular collisions are considered to be perfectly

A

Elastic

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12
Q

The absolute temperature is s quantity proportional to the average kinetic energy of all molecules in a system

A

Kinetic molecular theory

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13
Q

At relatively low pressures, the average distances between molecules are large compared with molecular diameters and hence the attractive forces between molecules may be considered negligible

A

Kinetic molecular theory

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14
Q

The vapor density method of the determination of molecular weight is developed by

A

Jean Baptiste Andre Dumas

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15
Q

The regnant method of the determination of molecular weight is developed by

A

Henry victor Renault

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16
Q

As soon as equilibrium is established between the liquid and vapor,mother pressure exerted by the vapor is known as the

A

Saturated vapor pressure

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17
Q

When the critical point is reached, there is or no distinction between the liquid and the vapor

A

No

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18
Q

The resistance offered by the fluid to the flow of another fluid

A

Viscosity

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19
Q

It is produced by the shearing effect of moving one layer of the fluid past another

20
Q

Viscosity increases with increasing temperature when it come to

21
Q

The pouiseuille equation is also known as

A

Ostwald viscosimeter

22
Q

This law if applicable with the radius of the falling body is greater than the distance between the molecules of the liquid

A

Stokes law

23
Q

The du Nouy Ring Method uses a device called

A

Tension enter

24
Q

The tensiometer was developed in

A

Rockefeller institute for medical research

25
Constituent structural units are arranged in a definite geometrical configuration characteristic of a substance. It melts sharply at constant and definite temperature
Crystalline
26
Solids which does not show definite configurational arrangement and are not considered as true solids but highly supercooled liquids with very high viscosity. It melts gradually over a temperature interval
Amosphous
27
The amount of heat evolved during crystallization or solidification per mile of substance at a given temperature and pressure
Heat of crystallization
28
The reverse of heat of crystallization which is the amount of heat that must be absorbed in the transition of one mole of solid to liquid
Heat of fusion
29
A study dealing with the geometry, properties and structure of crystals and crystalline substances
Crystallography
30
In a crystal system, there may be --- crystal forms
230
31
Crystal systems may be groups into --- classes according to symmetry
32
32
Existence of substanc s in more than one modification
Polymorphism
33
Polymorphism occurring in elements
Allotropy
34
The transformation from one form to another takes place at a temperature known as transition temperature of transition point
Allotropy
35
It produces electricity as a result of spontaneous reactions occurring inside it where the cathode has a higher potential than the anode
Galvanic cell
36
Non-spontaneous reaction is driven by an external source of current. They have a common electrolyte and no salt bridge
Electrolytic cell
37
Reduction occurs in the --- and oxidation occurs in the ---
Cathode | Anode
38
In electrolytic cells, the anode and cathode is
+ | -
39
In galvanic cells, the anode and cathode is
- | +
40
A reduction brought about by the passage of a direct current through a solution of an electrolyte
Electrolysis
41
The phenomena that occurs in electrolytic conduction
Mass movement of ions | Occurring of Oxidation-Reduction Reaction
42
The mass of a substance involved in the reaction at the electrode is proportional to the quality of electricity passed though the solution
Faraday's Law
43
Governs the temperature dependence of pressure in a two-phase, one component system
Chaperoning equation
44
Gives the r lotion ship between pressure and temperature for a two-phase, one-component system assuming that the vapor phase is ideal and the molar volume of the condensed phase is negligible compared to that of the vapor phase
Clausius-Clapeyron Equation
45
Solutions with heat of mixing equal to zero and the volume of the solution is the sum of the volumes of the components of the solution
Ideal solution