Physical Chemistry Flashcards
An ideal gas will only be considered in the
following operating parameters:
a. High Temperature, High Pressure
b. High Temperature, Low Pressure
c. Low Temperature, High Pressure
d. Low Temperature, Low Pressure
b
Which ofthe following isfalse regarding absolute
zero?
a. All molecules will stop moving
b. Absolute zero can be achieved
c. Temperature is 0K
d. Temperature is 0R
b
For a real gas, what causes the deviation from
the ideal pressure at a molecular level?
a. Energy is lost for each collision against
the sides of the container
b. Energy is lost due to the collision of
molecules with one another
c. Intermolecularforces of attraction of the
molecules with one another
d. Molecules randomly hit the sides of the
wall with less force than usual
c
When gas molecules collide, they experience
collision.
Perfectly Elastic
Which of the following is false with KMT?
a. Gas molecules move in random motion
b. Due to collision of gas molecules with
each other, some kinetic energy is lost
c. The temperature of the whole system
does not change with time
d. The size of the molecules are negligible
b
This is the pressure exerted by the gas molecules
that are in equilibrium with the liquid
Vapor pressure
The internal energy of an ideal gas depends on:
absolute temperature
Which of the following is a characteristic of an
adiabatic process?
a. ΔU=0 c. Q=0
b. W=0 d. ΔV=0
c
A sample of an ideal gas has an internal energy
of U and is then compressed to ½ of its original
volume while the temperature stays the same.
What is the new internal energy of the ideal gas
in terms of U?
a. U c. U/4
b. U/2 d. 2U
a
Which of the following is not conserved in any
process?
a. Mass c. Momentum
b. Energy d. Entropy
d
An isentropic process is:
a. Isothermal and adiabatic
b. Reversible and isothermal
c. Reversible and adiabatic
d. Reversible and isochoric
c
Increasing the temperature of the cold reservoir
the Carnot efficiency.
decreases
If the entropy of a system decreases,the entropy
of its surroundings
a. Must always increase
b. Must always decrease
c. May increase or decrease
d. Not enough information to answer the
question
a
The amount of heat absorbed when CO2 gas
reacts with a solid CaO to form solid CaCO3 is
measured in a bomb calorimeter. The data
obtained give a direct measure of:
internal energy
Heat required to raise the temperature of 1lbm
of water by 1˚F
BTU
Which of the following statements is/are true?
1. The criterion of equilibrium at constant
temperature and pressure is dG=0.
2. For a reversible process, dS=dQ/T.
both 1 & 2
The equilibrium intensive state of a system is
described by specifying the temperature,
pressure, and:
Mole fractions
The general statement of the Third Law of
Thermodynamicsis attributed to:
Walther Nernst
The fugacity of a real gas is equal to:
a. The pressure of an ideal gas which has
the same chemical potential as the real
gas
b. The pressure of a real gas which has the 𝑑𝐻 = 𝐶
same chemical potential as the ideal gas 𝜕𝑉
c. The chemical potential of an ideal gas
which has the same pressure as the real
gas
d. The chemical potential of a real gas
which hasthe same pressure as the ideal
gas
a
An adiabatic process is one in which the system
under investigation is thermally isolated so that
there is no exchange of heat with the
surroundings. Thus, the work done on a closed
system in an adiabatic process is _.
a. Equal to zero
b. Not equal to the exchange of heat with
surroundings
c. Equal to the increase in internal energy
of the system
d. Not equal to the increase in internal
energy of the system
c
State Le Chatelier’s Principle.
a. Le Chatelier’s principle states that when
a stress is placed on a system in
equilibrium, the system tends to change
in a way that relieves the stress.
b. All of these
c. Examples of the application of Le
Chatelier’s principle are blowing your
breath through a straw and dissolving
alka seltzer tablet in a glass of water.
d. Le Chatelier’s principle explains both the
formation and decomposition of acids,
where anything that might act to
increase the concentration of an acid
would produce an increase in the other
components so as to keep the numerical
a
A certain gas confined in a cylinder by a piston,
where the initial pressure in the system is 7 bar
and the volume is 0.11 cubic meter. The piston is
held in place by latches and the apparatus is in
vacuum. Determine the change in energy when
the latches are removed suddenly and the gas
expands to double its initial volume and the
piston strikes the latches at the end of the
process.
no change
Determine which of the following occurrences
tells us what happens when Le Chatelier’s
principle is applied whether these are true or
false.
1. The addition of a component causes the
equilibrium to shift to the opposite side
2. The removal of a component causes the
equilibrium to the side from which the
component is removed
3. Increasing the temperature drives an
exothermic reaction to the side of the
reactants, an endothermic equilibrium
to the side of the products
4. The addition of a catalyst has NO effect
on the position of the equilibrium
a. T, F, T, F
b. T, T, T, T
c. F, T, F, T
d. F, F, F, F
b
Define entropy.
a. Entropy is a function of the state of the
system and determines whether a
physical change or chemical reaction can
occur simultaneously in a closed system
b. Entropy is the opposite of enthalpy
c. Entropy determines the time required
for a reaction to proceed and complete
d. All of these
d
