Phosphorus Flashcards

1
Q

what group is phosphorus?

A

group fifteen

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2
Q

is phosphorus a metal or non metal?

A

metal

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3
Q

as a result of phosphorus being a metal what two qualities does it have?

A

non conducting

forms acidic oxides

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4
Q

when was phosphorus discovered?

A

1669

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5
Q

how was phosphorus first ?

A

by accident when a alchemist was trying to get gold from pee

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6
Q

what 3 qualities does white phosphorus have?

A

white
waxy
spontaneously combusts in air

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7
Q

is white phosphorus toxic?

A

to humans, yes

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8
Q

for over 100 years what was the main source of phosphorus?

A

pee

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9
Q

how is phosphorus obtained today?

A

obtained from calcium phosphate (apatite) (Ca3(PO4)2)

this mineral is heated with sand and coke to get white phosphorus

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10
Q

what is the shape of P4 (white phosphorus)?

A

tetrahedron (phosphorus in corners)

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11
Q

what are the bond angles in tertahedron?

A

all 60 degrees

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12
Q

what is the reason white phosphorus is so unstable and reactive?

A

because the 60 degree angles of the tetrahedron mean lots of bond strain

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13
Q

if white phosphorus is heated in the abscence of air to 300 degrees what happens?

A

it changes its structure to a different allotrope called red phosphorus

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14
Q

what is the structure of red phoshorus

A

tetrahedron with a bond moved to connect it to another tetrahedron, forms a chain

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15
Q

is red phosphorus as reactive and toxic as white phosphorus?

A

no

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16
Q

what is red phosphorus commonly used for?

A

match heads (of the strike anywhere sort)

17
Q

what form of phosphorus is used in match heads?

what oxidizing agent is added to this?

A

P4S3

KClO3

18
Q

how is black phosphorus obtained?

A

by heating white phosphorus under pressure

19
Q

how is black phosphorus in terms of stabilty and reactivity/

A

the least reactive and most stable of the three allotropes

20
Q

what range of oxidation states does phosphorus have?

A

-3 to +5

21
Q

which oxidizing state of phosphorus is the most stable

A

+5

22
Q

what is phosphorus’s valance electron configuration

A

3s2 3p2

23
Q

what is phosphine (PH3)?

A

a colourless, poisonous gas that smells like dead fish

24
Q

what is the oxidation state of phosphorus in phosphine?

A

-3

25
Q

how is the polarity of phoshine compared to that of ammonia?

A

less polar because phosphorus is less electronegative than