Oteher notes Flashcards
1
Q
H2SO4, H2O, HgSO4
A
OH at mark, then O
2
Q
H3O+, H2O
A
DB steals H on H3O+ , creating + tert carbon. Resonance forms Ketone (O=<) and H3O+
3
Q
BH3, TFH, H2O2, NaOH
A
Gets rid of 3x bond, O= at mark
4
Q
- O3
- H2O
Terminal alkyne
A
O=/OH added to both
5
Q
- O3
- H2O
Nonterminal alkyne
A
O=/OH added to R, C has 2x O=
6
Q
Alkylation of terminal acetylides, starting with terminal acetyline
A
NH2 takes an H off, E- take R from R-X. Can be done 2x to replace both H with R
7
Q
Radicals are > stable with
A
Bulkier structures
8
Q
KOT
HOT
A
Takes Br off, makes DB