Oteher notes Flashcards

1
Q

H2SO4, H2O, HgSO4

A

OH at mark, then O

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2
Q

H3O+, H2O

A

DB steals H on H3O+ , creating + tert carbon. Resonance forms Ketone (O=<) and H3O+

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3
Q

BH3, TFH, H2O2, NaOH

A

Gets rid of 3x bond, O= at mark

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4
Q
  1. O3
  2. H2O
    Terminal alkyne
A

O=/OH added to both

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5
Q
  1. O3
  2. H2O
    Nonterminal alkyne
A

O=/OH added to R, C has 2x O=

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6
Q

Alkylation of terminal acetylides, starting with terminal acetyline

A

NH2 takes an H off, E- take R from R-X. Can be done 2x to replace both H with R

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7
Q

Radicals are > stable with

A

Bulkier structures

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8
Q

KOT
HOT

A

Takes Br off, makes DB

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