Last minute prep Flashcards
1
Q
- McPBA
- H3O+
A
OH attacks O bonded across DB, then anti OH across DB
2
Q
- OsO4, H2O2
A
Syn addition of OH
3
Q
Kmno4, COLD
A
Syn addition of OH
4
Q
Temperature
A
Cold adds something, hot takes it off
5
Q
How to make OH leave
A
Turn it into a tosylate. Takes off H, puts TS. Uses MEOH to leave
6
Q
Move DB by adding to DB (Any __________), then _____________ (adding _____)
A
(Any addn reaction, halides especially), then doing elimination (adding TbuOK)
7
Q
Use smaller base for ____________ like _____
A
more sterically hindered area, MeO
8
Q
Can only use NBS with an _________________
A
alkane (no double bonds).
9
Q
MeO can add
A
methyl group
10
Q
NaNH2
A
Joins structures together or makes an alkyne
11
Q
NaNH3
A
Takes a bond off
12
Q
- O3
- DMS
A
Adds O
13
Q
t-buok
A
Does elimination, makes less sterically hindered product
14
Q
Add base to make a double bond
A
T-buOK
15
Q
Making an alkyne
A
- H2, PT
- XS NaNH2/NH3
- H2O
