Organic Synthesis Reactions Flashcards by Jess Sails

Q

primary amine –> N-substituted amide

A

acyl chloride

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Q

bromoalkane –> primary amine

A

NH3
reflux

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Q

alkane –> bromoalkane

A

Br2
UV light

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Q

alkene –> alkane

A

Ni catalyst
150 degrees and pressure

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Q

alkene –> dibromoalkane

A

HBr
20 degrees

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Q

alkene –> dibromoalkane

A

HBr
20 degrees

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Q

secondary bromoalkane –> secoondary alcohol

A

NaOH
reflux

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Q

bromoalkane –> primary alcohol

A

NaOH
reflux

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Q

alkene –> primary alcohol

A

H3PO4 catalyst
steam
300 degrees

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Q

primary alcohol –> alkene

A

conc. H2SO4
170 degrees and pressure

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Q

secondary alcohol –> ketone

A

K2Cr2O7
H2SO4
reflux

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Q

primary alcohol –> aldehyde

A

K2Cr2O7
H2SO4
heat then distil

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Q

ketone –> cyanohydrin

A

HCN

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Q

aldehyde –> cyanohydrin

A

HCN

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Q

aldehyde –> carboxylic acid

A

K2Cr2O7
H2SO4
reflux

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Q

primary amide –> carboxylic acid

A

H+ heat

Q

carboxylic acid –> ester

A

alcohol
H+ catalyst
reflux

Q

ester –> carboxylic acid

A

H+
reflux

Q

acyl chloride –> ester

A

alcohol

Q

benzene –> nitrobenzene
(NITRIFICATION)

A

H2SO4
HNO3
55 degrees

Q

sulfonation of benzene

A

fuming H2SO4
40 degrees

Q

acylation of benzene

A

RCOCl
AlCl3 catalyst
reflux

Q

alkylation of benzene

A

RCl
AlCl3 catalyst
reflux

Q

benzene –> chlorobenzene
(CHLORINATION)

A

Cl2
AlCl3 catalyst
warm

Q

phenol –> phenylethanoate

A

CH3COCl
20 degrees

Q

phenol –> sodium phenoxide

A

NaOH
20 degrees

Q

aminobenzene –> benzenediazonium chloride

A

HNO2/HCl
less than 5 degrees

Q

benzenediazonium chloride – yellow/orange azo compound

A

phenol
NaOH
less than 5 degrees