Organic Overview Flashcards
all of organic
What’s catalytic cracking
breaking down a large molecule into a smaller molecule using a catalyst
Do the melting and boiling points of alkenes increase or decrease as the carbon content increases
Increase
are hydrocarbon derivatives considered hydrocarbons
no because they include substances other then just hydrogen and carbon
what do you need to ensure when choosing your parent carbon chain in an alkene or alkyne
that the double or triple bond is included
whats another way to name 1,4 - dimethylbenzene
para-dimethylbenzene or p-dimethylbenzene
what does catalytic reforming usually produce
a gasoline with better burning properties
what do intermolecular forces describe
the attraction one molecule has for the others surrounding it
what does ortho mean
When the two branches are beside each other on a benzene ring
what happens to the strength of intermolecular forces the more types of the 3 forces the molecule has
the strength of the intermolecular forces increases as the type of organic substance has more of the 3 forces
Why are cycloalkynes rare
because of angle stress
whats a tertiary/third degree alcohol
alcohols where the carbon atom with the -OH group is bonded to 3 other carbon atoms
what is the requirement for a compound to be able to undergo a substitution reaction
It must be saturated
how do you view and what do you call organic compounds that contain elements other then hydrogen and carbon
view them as being derived from a hydrocarbon by replacing on eor more of the hydrogens to the parent molecule by other atoms or groups of atoms; they are called hydrocarbon derivatives
Prefix for three
propa
what makes up the functional group of an ester
carbon double bonded to an oxygen and single bonded to another oxygen
what is an esterification reaction
the reaction between a carboxylic acid and an alcohol in the presence of a catalyst to produce an ester
what are elimination reactions a primary source for
alkenes produced from either alcohols or alkyl halides
what makes up the functional group for a carboxylic acid
the addition of a carbon double bonded to an oxygen and single bonded to an OH group
are alkane physical property similar to alkenes? if so why
Their physical properties correspond to properties of similarly sized alkanes because alkenes are also nonpolar
what states are pure hydrocarbons containing 18 or more carbons in
waxy solids
whats an aromatic
substances that consist of one or more rings that contain alternating single and double bonds in its chemical structure
What is the unique types of reactions that alkanes undergo
Substitution reactions
whats the prefix for flourine
fluoro
What type of bonds are present in an alkyne
Triple bonds
Why do larger alkane molecules have higher boiling points
The strength of the London dispersion forces increase with an increase in the number of electrons
are halides polar or non-polar
polar on the halide side of the molecule but non-polar on the hydrocarbon end
how many carbons can be in a carboxylic acid for it to be soluble in water
between 1 and 5 carbons; if the acid has 6 or more carbons it will become insoluble in water
what is the first member of the alkane series
CH4
whats crude oil
a mixture of hydrocarbons with different chain lengths
what states are pure hydrocarbons containing 5-17 carbons in
liquid
What’s an example of an oxide of carbon
CO, CO2
How do you name a benzene ring if an alkyl group is bonded to it
alkylbenzene
whats the prefix for bromine
bromo
What’s a full structural formula
When you expand on all of the hydrogen bonds
when are prefixes cis and trans used
when naming/identifying the shape of cyclic structures or structures including a double bond
how are alcohols prepared
by reacting alkenes with water
what do alcohols produce when they undergo elimination reactions
alkenes
How does the amount of inorganic reactants correlate to how many bonds will be broken in the hydrocarbon
One bond broken per one mole of the inorganic additive
Reagents alkenes undergo substitution with
Halogens
If a molecule is cyclo is it boiling point higher or lower
higher
What type of intermolecular forces exist between alkane molecules
Only London dispersion forces
What’s a cycloalkene
Ring structures containing a double bond
what is the general formula for a cycloalkane
CnH(2n)
whats another way to name 1,2 - dimethylbenzene
ortho - dimethylbenzene or
o-dimethylbenzene
How do number of bonds in a molecule directly affect the boiling point
The more bonds in the molecule the higher the boiling point
what are the categories of organic compounds that are poor-insoluble in water (5)
- all pure hydrocarbons are insoluble
- all alkyl halides have little to no solubility
- alcohols with 4-6 carbons have really low solubility
- bigger then 6 carbon alcohols are insoluble
- carboxylic acids bigger than 4 carbons have poor solubility and become insoluble the bigger they get
how do you name an alcohol if there is more then 1 hydroxyl (OH) group
keep the parent name the same and add ‘diol’ for 2 OH groups or ‘triol’ for 3 OH groups
whats another name for the halide derivitive
organic halides or alkyl halides
What does the prefix of the parent name indicate
Number of carbon atoms in the structure
are alcohols soluble in water, why or why not
they are also soluble in water because they can hydrogen bond
What is the biggest bond difference between a cyclic compound and its noncyclic compound
The cyclic compound contains two less hydrogen atoms than the noncyclic compound with the same number of carbon atoms
how does the size of a halide affect its solubility
the larger the hydrocarbon end of the halide, the more soluble it is with a non-polar solvent
what does it mean when a compound is saturated
The carbon atoms are making the maximum amount of bonds
what is the strongest type of intermolecular force
hydrogen bonds
whats the prefix for iodine
iodo
whats the minimum amount of carbons needed to make a cyclic shape
3
What is cracking
When larger alkanes are broken into smaller parts
what is the general formula for a carboxylic acid
R-COOH where R is an alkyl group
what are polymers
very large molecules made by bonding together many smaller molecules
how do you name a carboxylic acid
select the longest carbon chain containing the carboxylic carbon and replace the final -e of the alkane name with the ending -oic acid
Are cyclic compound saturated
no
How are organic compounds separated into families
Based on their structure As well as their physical and chemical properties
What’s another name for refining reaction
Ethene cracking
what process is going on in a fractional tower
separation of different hydrocarbons based on boiling points, temperatures and condensing vapors
what does a homologous series mean
group of organic compounds that share the same functional group and have similar chemical properties, but differ by a regular, repeating unit, typically a -CH₂- group; as the series continue, each structure is getting larger
what gives the characteristic properties to an organic molecule
the attached atoms or groups
what is it called when water is eliminated/removed from an alcohol
dehydration
Prefix for nine
nona
what are the different types Of pure hydrocarbons
Aliphatics and Aromatics
how does a fractional distillation tower work
it contains trays positioned at various level. The bottom of the tower is kept hot and the temperature gradually decreases towards the top of the tower. Heated crude oil enters the tower. Hydrocarbons with the lowest boiling point travel to the top of the tower and substances with the highest boiling point stay at the bottom of the tower
what type of force does a molecule need to have in order to be considered polar
dipole-dipole forces
whats organic chemistry
chemistry of carbon containing compounds
Are alkanes able to undergo an addition reaction
no
what type of organic compounds are dipole-dipole induction forces and hydrogen bond forces present in
only present in hydrocarbon derivitives
how many parts of a diatomic halogen are substituted during a substituion reaction
one
how do you name benzene if there is a branch on the attached hydrocarbon chain or a double/triple bond is present
benzene then becomes named as a branch and is called ‘phenyl’
what happens during dehydrohalogenation
a hydrogen and halogen atom from adjacent carbon atoms are eliminated
what the biggest difference between addition and condensation polymers
addition polymers dont produce any products, condensation polymers do produce by products
where on the periodic table are the electronegativity’s located
right underneath the atomic number
what is the product of a substituiton reaction
a small inorganic product
what will pure hydrocarbons dissolve in
other liquid pure hydrocarbons
how is a condensation polymer formed and what do they produce
formed when two monomers are joined with the simultaneous elimination of a small molecule; often form water as a by product
whats another way to name 1,3 - dimethylbenzene
meta-dimethylbenzene or m-dimethylbenzene
what makes up the functional group for a halide
F, Cl, Br, I
assuming there isnt a double or triple bond present, where do you add the name of the alcohol
to the end of the parent/main name
are alkene saturated or unsaturated hydrocarbons
unsaturated because of their double bond
what happens to london dispersion forces as atoms get larger
the forces get stronger/larger
what does ‘cis’ mean
when the branches/groups are located on the same side of the structure
why is the alkane series considered homologous
Because the sequence of molecules have similar structures but differ in the number of repeating units
whats a binary molecular compound
compound with 2 different elements
how is the amount of stress on a structure affected by the number of bonds present
the more bonds present, the more stressed the structure is
what two groups are organic compounds composed of
a hydrocarbon part (R for aliphatic or Ar for aromatic) and one or more functional groups
What a substitution reaction
When a halogen atom may be substituted for a hydrogen atom in a straight or branched carbon chain
are carboxylic acids polar or non-polar
polar
list the halides in order of highest intermolecular forces to lowest intermolecular forces
iodides, bromides, chlorides, flourides
what happens to melting/boiling points the stronger the intermolecular forces present are
the stronger the forces are, the more energy it takes to break them apart making their melting/boiling/breaking point higher
what type of reaction can specifically alkyl halides undergo
an elimination reaction alled dehydrohalogenation
whats functional group do alcohols contain
minimum of 1 hydroxyl (OH) group
what is the most reactive type of hydrocarbon
alkynes
how do you name an ester
name the alkyl group from the alcohol first the replace the -ic ending of the carboxylic acid with the ending -ate to form the second part of the esters name
what are halides soluble with
polar and non-polar hydrocarbons
what do branches do to the strength of intermolecular forces
they make them weaker
What types of substances do alkenes and alkynes undergo addition reactions with
Hydrogen, hydrogen halides, water and the halogens
what reactions can alcohols undergo
both types of combustion and elimination reactions
what are esters responsible for
many of the characteristic tastes and odours of our foods
what is fractional distillation
method used to separate hydrocarbons into different fractions based on boiling points
What is the general rule regarding solubility and polarity
The longer the parent carbon chain is the lower its solubility and the less polar it will be
do cyclo shapes have lower or higher boiling points in their corresponding straight chain shape
Higher boiling points because they are more dense
whats the first member of the alkene series
C2H4
How is cracking accomplished
At high temperatures in the absence of air or by using catalysts
what happens to the polarity of a hydrocarbon derivative as it gets larger
the larger the molecule, the less polar it is
Prefix for four
buta
when do hydrogen bonds occur
when a hydrogon bonds to an extremely electronegative atom which then causes bery strong polar opposite areas in the molecule that border on almost being ionic in strength
list the halides in order of highest boiling/melting points to lowest boiling/melting points
iodides, bromides, chlorides, flourides