La Chateleirs Principle Flashcards

1
Q

what is la chatliers principle

A

when a system at equilibrium is disturbed, the new equilibrium shifts in the direction that opposes the change, until a new equilibrium is reached

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2
Q

what are the three common ways an equilibrium may be disturbed

A

change in the concentration of a reactant or product, change in temperature, change in the volume

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3
Q

what happens if you change the temperature of a reaction by more then a few degrees

A

the Kc value will change

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4
Q

according to le chatliers principle, what will happen to the reaction if it is disturbed by the addition of a product/the removal of a reactant

A

the equilibrium will shift right

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5
Q

what does the equilibrium do when you add something

A

it works away from whatever you add

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6
Q

what does the equilibrium do when you remove something

A

it works towards whatever you remove

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7
Q

what shifts occur in an equilibrium when you add or remove solids

A

no shifts occur when you add/remove solids becuase they are constant and do not appear in expressions for K

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8
Q

how does a graph show that a substance has been added or removed from an equilibrium

A

a spike in either a reactant or product (just one) will occur, and a gradual change will be present in the other entities

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9
Q

what does adding something do to that substances concentration

A

it increases it

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10
Q

what does removing something do that substances concentration

A

it decreases it

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11
Q

what happens when you add more of a reactant

A

more products will be produced

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12
Q

what happens when you remove some of a reactant

A

less products will be produced

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13
Q

what happens to temperature if energy decreases

A

temperature decreases

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14
Q

what happens to temperature if energy is increased

A

temperature increases

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15
Q

what happens if you increase the temperature in an endothermic reaction where heat acts like a reactant

A

the reaction shifts to the right

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16
Q

what happens if you decrease the temperature in an endothermic reaction where heat acts like a reactant

A

the reaction shifts to the left

17
Q

what happens if you increase the temperature in an exothermic reaction where heat acts like a product

A

the reaction shifts to the left

18
Q

what happens if you decrease the temperature in an exothermic reaction where heat acts like a product

A

the reaction shifts to the right

19
Q

what happens if the K value gets bigger and how does this shift the reaction

A

more products are being created which shifts the reaction to the right

20
Q

what is Kc dependent on

A

temperature

21
Q

how do temperature/energy changes appear on a graph

A

as gradual change with an opposite change in the products

22
Q

is there any spikes present in an energy change graph

A

no spikes, on gradual changes

23
Q

what happens to pressure if volume is decreased

A

pressure increases

24
Q

how does a decrease in volume affect an equilibrium

A

it causes the reaction to shift in the direction which contains the fewest moles of gas

25
Q

how does an increase in volume affect an equilibrium

A

it causes the reaction to shift in the direction which contains the most moles of gas

26
Q

what happens to pressure if volume is increased

A

pressure decreases

27
Q

what type of relationship do volume and pressure have

A

an inverse relationship so that when one substance increases or decreases the other does the opposite

28
Q

what happens if both sides of a chemical equation have the same number of moles of gas

A

the change in volume of the container has no effect on the equilibrium

29
Q

what happens to the K value of a reaction when a catalyst is added

A

there is no effect on its magnitude because catalysts increase both the forward and backward rate of reaction

30
Q

does a catalyst affect equilibrium

A

no

31
Q
A