Organic Chemistry Flashcards

1
Q

hydrocarbons

A

compounds made of carbon and hydrogen (no other elements)

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2
Q

what is the simplest hydrocarbon?

A

CH4 (methane)

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3
Q

saturated hydrocarbons

A

alkanes and cycloalkanes

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4
Q

unsaturated hydrocarbons

A

alkenes and alkynes

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5
Q

aromatic hydrocarbons

A

benzene rings

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6
Q

cyclic

A

no ends; resembles a ring

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7
Q

acyclic

A

a molecule with at least 2 ends

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8
Q

sp3 hybridized

A

four bonding directions (s+p3= 1+3= 4 orbitals)

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9
Q

alkanes

A

only single-bonded

  • sp3 hybridized
  • tetrahedral
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10
Q

alkene

A

possesses at least one double bond

  • sp2 hybridized
  • trigonal planar
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11
Q

alkyne

A

possesses at least one triple bond

  • sp hybridized
  • linear
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12
Q

benzene ring

A

six-membered ring with three alternating carbon-carbon double bonds

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13
Q

alkane hydrogen formula

A

C(n)H(2n+2)

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14
Q

meth-

A

one carbon

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15
Q

eth-

A

two carbon

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16
Q

prop-

A

three-carbon

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17
Q

but-

A

four carbon

18
Q

heteroatoms

A

atoms other than carbon and hydrogen

19
Q

alkyl

A

hydrogen along the parent chain of an alkyl is replaced with CH
-yl suffix

20
Q

nomenclature for a single alkyl group on a parent chain

A

-alkyl group/parent name (3-methyloctane)

21
Q

nomenclature for multiple alkyl groups on a parent chain

A

-alkyl group-#-alkyl group-parent name (4-ethyl-5-methyl-decane

22
Q

alcohols

A

contains O-H functional group

  • R1-OH
  • suffix -ol is added
23
Q

ethers

A

contains C-O-C functional group (oxygen bonded between two carbon rings/chains)

  • R1-O-R2
  • name by finding the number of carbons on both sides of the oxygen, using the base names from those, adding the -yl suffix on each, and adding ether (ex: butyl ethyl ether)
24
Q

structural isomers

A

same molecular formula, different molecular structures (NOT THE SAME AS AN ALLOTROPE)

25
Q

geometric isomers

A

when there are two different groups located on the alkene’s double-bonded carbon

26
Q

internal alkyne

A

found inside of the carbon chain of the molecule

27
Q

terminal alkyne

A

found at the end of the carbon chain of the molecule

28
Q

trans- geometric isomer

A

when the larger groups are on the opposite sides of the double bonds

29
Q

cis- geometric isomer

A

when the larger groups are on the same sides of the double bonds.

30
Q

carbonyls

A

contains C=O functional groups

31
Q

aldehyde functional group

A

contains C=O and a bonded hydrogen (a compound with a carbonyl group bonded at the end of a carbon chain with a carbonyl group bonded to a carbon atom on one side and a hydrogen atom on the other)
O
| |
R1 - C - H
-when naming chains, add the suffix -al
-when naming ring structures, add “carbaldehyde”.

32
Q

ketone functional group

A

contains C-C(=O)-C (carbonyl group is bonded to two carbon atoms)
O
| |
R1 - C R2
-replace “e” at the end of the parent chain with the suffix -one.

33
Q

carboxylic group

A

contains COOH (CO2H) functional group (a carbonyl group bonded to a hydroxyl group)
O
| |
R1 - C -OH
-replace “e” at the end of the parent chain with the suffix -oic and add the word “acid”.

34
Q

ester

A

sp3 hybridized oxygen is connected to an alkyl group (an organic compound in which the hydrogen of the hydroxyl group of a carboxylic acid is replaced by either an alkyl group or a carbon chain)
O
| |
R1 - C -O -R2
-replace the e ending of the parent name with the suffix -oate (ex: methyl propanoate)

35
Q

amines

A

compounds derived from ammonia (NH3). created by replacing one or more hydrogen atoms with alkyl groups.(a nitrogen atom bonded to a carbon atom in a chain or a ring)

  • R1-NH2
  • change the ending of the parent chain to -yl and add “amine”
36
Q

Organic compounds are often held together by ___ bonds

A

covalent

37
Q

Elemental carbon’s 4 solid forms:

A
  • amorphous carbon
  • graphite
  • diamond
  • buckministerfullerene (C60)
38
Q

Carbon Chain

A

two or more carbon atoms that are bonded without forming a ring

39
Q

halocarbons

A

any organic molecules containing a halogen substituent group

  • R1 - X (R1=carbon chain, X= any halogen)
  • prefix of halogen is added
40
Q

Phenol

A

A benzene ring with a hydroxyl group attached

41
Q

Benzaldehyde

A

An aldehyde with a benzene ring

42
Q

Amides

A

when the OH of carboxylic acid is replaced by a nitrogen group
O
| |
R1 - C -N -R2
-replace the “e” with “amide”. (Butanamide)