Organic Chemistry Flashcards
Dicarboxylic acid- hexanedioic acid
HOOCCH2 CH2 CH2 CH2 COOH
What is condensation polymerisation
The addition of two monomers which releases a small molecule- normally water
Diamine- diaminohexane
H2 NCH2 CH2 CH2 CH2 CH2 NH2
Complete combustion
Propane + oxygen –> carbon dioxide + water
C3H8 + 5O2 –> 3CO2 + 3H2O
Incomplete combustion
Ethane + oxygen –> carbon monoxide + carbon (soot) + water
C2H6 + 2O2 –> CO + C + 3H2O
What is complete combustion
When an alkane is burned in excess oxygen
What is incomplete combustion
When and alkane is burned and there isn’t enough oxygen for complete combustion
What is a hydrocarbon
Substance made only from carbon and hydrogen atoms
Fractional distillation from top to bottom
Refinery gases Gasoline (LGP) Naptha Kerosine Diesel Fuel oil (refinery gases) Bitumin
How does temperature differ in the fractional distillation column
Increases in temperature as you move downwards
What physical property of hydrocarbon separates them in fractional distillation
Boiling point
How does the fractional distillation column work
The temperature changes throughout the the column so that the different fractions boil and different points and are released as gas at different levels
Why use fractionating columns
Allows crude oil to separated into different fractions and used according to their different properties
What is a functional group
The part of a molecule which gives it it’s functional purpose
Alkene general formula
CnH2n
Alkane general formula
CnH2n+2
Test for alkane vs Alkene
When an Alkene is mixed with bromine water it turns colourless as the double bond is broken so bromine atoms are separated
First 4 alkenes
Ethene (C2H4)
Propene (C3H6)
Butene (C4H8)
Pentene (C5H10)
Bromine water reaction
Methane + bromine –> bromomethane
CH4 + Br2 –> CH3Br +HBr
What’s an addition reaction
Alkenes + halogens
First 4 alkanes
Methane (CH4)
Ethane (C2H6)
Propane(C3H8)
Butane (C4H10)
Isomer of butane
Methylpropane
Isomer of pentane
Methylbutane
Dimethylpropane
Isomer of butene
But-1-ene
But-2-ene
Methylpropene
Why does fractional distillation work
Crude oil is a mixture and the compounds are not chemically bonded
What does the term ‘sweet and sour mean’
Term applied to crude oil when the hydrocarbons don’t contain sulphur only hydrogen and carbon
Difference between cyclopropane and propane
Cyclopropane has one hydrogen less
What other physical properties differ in the fractional distillation column and how
Viscosity
Carbon atoms
Increases downwards
Order ethane, propane, butane and pentane in most to least viscous
Pentane
Butane
Propane
Ethane
Order ethane, propane, butane and pentane in most to least volatile
Ethane
Propane
Butane
Pentane
Why does propane have a higher boiling point than methane
Propane has more covalent bonds/more electrons so more intermolecular forces must be broken
What’s isomerism
Compounds with the same molecular formula but different displayed formula (isomers)
Problems caused by carbon
Pollution- global dimming and smog
Breathing problems
Why can nitrogen and oxygen react in a car engine
Nitrogen is normally very un reactive but in vigorous conditions in car engine with high heat atoms will have a lot of engine and will react
Environmental problems caused my oxides of nitrogen
Nitrous oxide and sulphuric dioxide leads to acid rain
Describe experience for ethene
Bromine water is orange
Ethenes double bond reacts and bond between two bromine atoms is split
This turns it colourless
Temp and atmosphere for catalytic cracking
600 degrees
Porcelain chips
Name of monomer into name of polymer
Add poly to start of name
How do addition and condensation polymerisation differ
Addition is only one monomer
Condensation is two alternating monomers
Condensation a small molecule is released
Product made from polypropene
Plastic ropes
What is nylon
Polyamide
Yeast fermentation with oxygen
C6H12O6 + 9O2 –> 6CO2 + 6H2O
Yeast fermentation without oxygen equation
C6H12O6 –> 2CO2 + 2CH5OH
How does yeast react with no oxygen
It respites anaerobically
How to distil alcohol
Filter the mixture through filter paper and funnel into a boiling tube
Put bung into boiling tube with delivery tube and but the boiling tube into boiling water
The alcohol should distil
Distilled ethanol
Ethanol distillate
Does ethanol distillate ignite easily
Yes but the liquid does ignite, the fumes above it does
Flame from ignited ethanol distillate
Blue on surface and orange further up
Photosynthesis equation
6CO2 + 6H2O –> C6H12O6 + 6O2
Combustion of ethanol equation
2C2H5OH + 3O2 –> 2CO2 + 3H2O
Hydration process
Alkenes from cracking are reacted with steam phosphoric acid catalyst at 300 degrees and 60 atmospheres
Ethene +water
Ethanol
Why is ethanol produced synthetically not carbon neutral
It doesn’t take any CO2 from the atmosphere but it emits carbon monoxide and produces carbon
Why is ethanol produced through fermentation carbon neutral
Because it begins with photosynthesis which takes CO2 from the atmosphere so when it emits some, it does not exceed what it has taken
What’s ethene used for
Synthesising ethanol for fuel
Making plastics
Benefits of dehydrating alcohol
Alternative fuel source and its a different way of making Alkenes
What happens during dehydration
The molecules functional group is changed
Why dehydrate ethanol
Produces a fuel as you can’t use Alkenes as fuel because they don’t combust clearly of produce much what energy
Oxidation
Adding an oxygen with a double bond turns and alcohol into a carboxylic acid
Oxidation and electron number
Directly proportional
Oxidation
Loss of electrons
Reduction
Gaining electrons
When you leave an alcohol exposed to air what happens
It oxidises and become vinegar
Acid + carbonate –>
Carbon dioxide + salt + water
Ethanoate and sodium
The sodium is electrostatically bonded and this makes an ionic compound
Homologous series
Series of organic compounds which have the same general formula similar reactions but differ by CH2 group
General formula
States ratio of atoms in a homologous series
Isomerism
Compounds with same molecular formula and differed displayed formula- isomers
Isomer of butene
Mehypropene
And alkene + bromine water
Dibromethene
Viscosity, boiling point and carbon atoms in fractional column
Increases downwards
Dangers of carbon monoxide
Resources the capacity of the blood to carry oxygen as it binds to haemoglobin
Cracking conditions
Silica/alumina as catalyst
600-700 degrees
What’s does cracking do
Turns a long chain alkane into a shorter chain alkane and and alkene
Uses of fractions in column
Refinery gases- bottle gas Gasoline- petrol for cars Kerosene- fuel for aeroplanes Diesel oil- fuel for large vehicles Fuel oil- fuel for ships Bitumen- road surfaces