Organic Chemistry Flashcards

1
Q

Explain the fermentation process of alcohols,wine and the advantages/disadvantages of

A

Extract glucose from crops
Add yeast to the glucose (enzymes in the yeast act as a catalyst)
Fermentation takes place at 30-40 degrees
It is a batch process
Carbon dioxide is released
Advantages-
More carbon neutral
Cheap equipment needed for the Batch process
Sugars used are a renewable source

Disadvantages-
It takes time (time consuming) very slow process
Batch process has high labor costs
Very impure so it needs fractional distillation which takes time and is expensive.

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2
Q

Why is fermentation an anaerobic process?

A

Because oxygen is not required in the production of ethanol during fermentation.

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3
Q

What is the process of the Hydration of ethene? What are the advantages and disadvantages?

A

1- extracting crude oil from the ground
2- crude oil will be placed in the fractional distillation and cracking to get ethene
3- ethene is then hydrated (phosphoric acid is used as the catalyst, high temperatures and pressure is used)

Advantages-
Pure product
Fast reaction
Continuous ( cheaper manpower)

Disadvantages-
High energy is used which can be expensive (high temperature and pressure)
High costs for the equipment needed
Ethene is non renewable

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4
Q

Why is Ethanoic acid a weak acid?

A

Because it’s a carboxylic acid, and every 3 molecules only 1 is partially ionised which makes carboxylic acids including ethanoic acid to be weak due to partial ionisation.

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5
Q

Why do carboxylic acids make the solutions acidic?

A

When ionisation is complete, H+ ions are released

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6
Q

How can ethanol turn into ethanoic acid? And by what?

A

Ethanol can be oxidised to ethanoic acid by chemical oxidising agents

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7
Q

What are the functional group that you need to add to the structures of carboxylic acids, esters, alcohols-

A

OH- = alcohol
COOH = carboxylic acids
COO = esters

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8
Q

What do carboxylic acids react with? What do they produce whilst reacting?

A

React with carbonates to produce carbon dioxide, hydrogen, and a salt

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9
Q

Explain why the solution of Ethanoic acid has a different PH than hydrochloric acid-

A

Ethanoic is a weak acid ( less acidic than hydrochloric acid)
Ethanoic acid does not ionise completely in water
Less H+ ions produced
So Ethanoic acid will have a higher PH than HCL since it is weaker

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10
Q

State two uses of esters-

A

Flavorings, perfumes (they give a nice scent)

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11
Q

What needs to be reacted together to produce an ester?

A

Carboxylic acid and alcohol

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12
Q

How can ethyl ethanoate be produced?

A

Ethanoic acid and ethanol

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13
Q

What is the by product that is produced whilst reacting both alcohols and carboxylic acids to produce esters? What is the formula of that by product?

A

Water ( H2O)

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14
Q

What needs to have the double bond connected to a carbon atom?

A

Oxygen needs to have a double bond connected to the carbon atom

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15
Q

What is the catalyst used to produce esters? And is it a reversible reaction whilst producing esters?

A

Sulphuric acid is used. Yes since water and ester is able to form back into the alcohol and carboxylic acid.

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16
Q

What are the root words for carboxylic acids, alcohols, esters: and give examples-

A

Carboxylic acids: -noic Ethanoic methanoic
Alcohols: -nol
Esters: -noate ethanoate, methanoate, propanoate

17
Q

What happens in a thermal decomposition reaction?

A

Heat is used to break down large/long molecules into shorter molecules

18
Q

What type of reaction uses thermal decomposition?

A

Cracking

19
Q

What does cracking produce?

A

Shorter hydrocarbon chain and an alkene

20
Q

What is a hydrocarbon?

A

A compound made from hydrogen and carbon

21
Q

Why is aluminum oxide or broken porcelain used in cracking?

A

They act as a catalyst which speeds up the rate of a reaction

22
Q

Cracking produces a mixture of products, this mixture contains hydrocarbons with different boiling points, what method can be used to separate this mixture?

A

Fractional distillation

23
Q

Why is cracking used in the oil industry? 3 marker

A

Cracking involves thermal decomposition which helps breakdown large molecules into smaller molecules by using heat. 1 mark

There is more large hydrocarbons being produced than needed, 1 mark
So cracking is used to increase the supply of smaller hydrocarbons since they flow more easily. 1 mark

24
Q

What is cracking used for? And where are they used?

A

To produce petrol for cars
To produce alkenes which is a raw material for the plastic industry
To produce hydrogen gas for the production of ammonia

25
Q

Compare between small hydrocarbons and large hydrocarbons-

A

Small hydrocarbons- low boiling points, easy to ignite (to heat), more volatile so they’re useful as fuels.
Large hydrocarbons- high boiling points, harder to ignite, less volatile so they’re useful not useful as fuels

26
Q

Where are the large hydrocarbons being produced? What is used to make them smaller?

A

From fractional distillation large hydrocarbons are produced, cracking is used to produce smaller hydrocarbons since they’re much more useful.

27
Q

Other people say that increasing the production of ethanol from sugar cane will be
bad for the environment.
Suggest two reasons why.

A

Production of ethanol will cause a destruction of habitats to grow the crops.

Production plants for ethanol causes visual pollution

28
Q

Compounds A and B are both colourless liquids.
A test tube contains a colourless liquid, which could be either compound A or
compound B.
Describe a simple chemical test to show which compound, A or B, is in the test tube.

A

Add hydrogen carbonate.
If the test tube contained compound A, carbon dioxide will be released.
If the test tube contained compound B, carbon dioxide will not be released.