organic chemistry Flashcards

1
Q

organic

A

compounds containing carbon as the main component (also H,O)

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2
Q

hydro carbons

A

compounds containing carbon and hydrogen only

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3
Q

homoglous series

A

groups of chemicals with the same general formula, a pattern of physical properties, similar properties.

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4
Q

what is an alkane

A

it is a hydrocarbon containing only single bonds

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5
Q

what is the general formula for an alkane

A

CnH2n+2

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6
Q

how do you know how many carbons there are in an alkane

A

the root of the name tells us

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7
Q

no. of carbons in alkanes:
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.

A

root in alkane name
meth
eth
prop
but
pent
hex
hept
oct
non
dec

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8
Q

physical properties of an alkane

A

covalent discrete
- are oils
- the larger the molecules the more IMFs so the higher the tempreture
- viscosity, larger molecules are more viscous
-volatility, smaller the molecules the more volatile
- colour: small= colourless, medium=yellow, large=black

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9
Q

what is viscosity

A

the resistance to flow

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10
Q

what is volatility

A

the ease of turning into a gas

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11
Q

empirical formula

A

the lowest ratio of elements within a compound

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12
Q

molecular

A

the number of atoms of each element in a molecule

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13
Q

structural

A

the atoms connected to each C atom, listed in order

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14
Q

displayed

A

the exact bonds connecting each atom in a molecule

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15
Q

general

A

the mathematical equation that can be used to determine the number of one element compared to another

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16
Q

isomers

A

compounds with the same molecular formula but a different arrangement of atoms (different structural formula) and different physical properties

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17
Q

what is the root in isomers

A

the longest chain of carbons

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18
Q

measuring enthalpy change of HCL + Mg

A
  1. measure 10cm3 of HCL into a calorimeter
  2. measure 0.30g - 0.50g of Mg
  3. record initial temp. of acid
  4. add Mg to HCL and start timing
  5. record temp. every 15s until it has been decreasing for 45s
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19
Q

what 3 types of reactions do alkanes undergo

A

substitution
decomposition
combustion

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19
Q

why are alkanes generally unreactive

A

they contain only strong covalent bonds (saturated). energy need to be provided to cause a reaction (Ea)

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19
Q

how can energy be provided as for alkanes reactions

A

heat
light
electricity

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20
Q

substitution with halogens

A

requires UV light
alkane + halogen —-> haloalkane + hydrogen halide

21
Q

complete combustion reaction

A

alkane + oxygen —-> carbon dioxide + water

22
Q

incomplete combustion reaction

A

alkane + oxygen —> carbon monoxide + water

23
decomposition (cracking)
heat - 300c catalyst - Al2O3 SiO2 C16H34 ----> C9H20 + C7H14
24
general formula for an alkene
CnH2n
25
alkene
hydrocarbons containing atleast one C=C
26
Physical properties of an alkene
same as alkane only the mpt/bpt is lower because they have fewer IMFs
27
chemical properties of an alkene
bonding a is strong whereas bonding b is weak in a double bond. this causes the bonding b to break easily allowing addition reactions to take place.
28
what is polymerisation
is a reaction involving alkenes addition reaction ethene ---> polyethene product does not have any c=c
29
physical properties of polymers
low mpt. discrete covalent do not conduct insoluble in water soluble in oil
30
chemical properties of polymers
unreactive (saturated) except for substitution or decomposition
31
method 1 of manufacturing ethanol
direct hydration of ethene ethene + water ---> ethanol addition/hydration reaction
32
what is ethanol used for
disinfectant as a solvent
33
advantages of method 1 of manufacturing ethanol
continuous process (continues to the product) makes the pure product, no separation required
34
disadvantages of method 1 of manufacturing ethanol
high energy demand non-renewable ethene needs manufacturing expensive
35
method 2 for manufacturing of ethanol
fermentation of sugars sugar ---(yeast)--->ethanol + CO2 we use fruits for the sugar
36
advantages for method 2 for manufacturing of ethanol
low energy required can drink, because it has fermented sugars in it (not pure, flavoured ethanol renewable
37
disadvantages method 2 for manufacturing of ethanol
batch process (opposite of continuous) not pure ethanol, if it is above 15% then it kills the yeast (distillation can be used to increase the concentration)
38
what is crude oil
is a mixture of alkanes which formed from the remains of sea creatures which have reacted to form organic compounds it is a mixture of 1000s of miscible substance all with different boiling points
39
laboratory separation
fractional distillation heat in intervals of 40 degrees otherwise it takes to long to separate them all this separates them into mixtures with similar bpt.
40
what does R represent in a compound
any chemical
41
what is a reflux
to oxidide an alcohol you need to heat it up using a reflux. this stops the alcohol evaporation. this is so it has time to react
42
what are polymers
long chain of 1000s of small alkene molecules joined together often used as plastic
43
how do alkenes react
by breaking the weakest bond in the double bond
44
how do you dispose plastic
in a landfill of by burning but best is to recycle
45
what makes alcohols different from alkanes
contain OH
46
how do we make alcohols
alkene + water
47
what does the capital R represent in a displayed formula
any chemical
48
how are esters formed
by reacting alcohols with carboxylic acids reaction is called condensation two molecules are made and one water molecule is removed
49
how to name esters
name of alcohol but prefix (yle) + name of acid but with suffix oate
50
how can u increase esterification
using a catalyst= concentrated H2SO4 increase the temp(70) use reflux for temp
51
how do you make polyesters
dicarboxylic acid + dialcohol (diol) (dioic)
52
how are condensation polymers formed
from two types of monomers