acids and bases Flashcards
acids
a substance that produces H+ ions
in a solutions their pH is <7
HCl, HNO3, N3PO4, H2SO4 all produce h+ ions in water
non- metal oxides e.g. CO2
CO2 + H2O —> H2CO3
H2CO3 —> 2H+ + CO3 2-
bases
metal oxides, metal hydroxides, metal carbonates, ammonia
substances that react with acids to create water
alkali
a base that dissolve in water
gp 1 hydroxides/ carbonates
the pH scale only measures substances that are dissolved in water
neutralization
a reaction of an acid and a base to produce water
proton transfer reaction
consentration
measures the moles of a solute dissolved in a specific volume of solvent
conc. of an acid
a measure of the no. of mols dissolved in water. any acid can have any concentration
what does the strength of an acid depend on
degree of dissociation
e.g. of strong and weak acid
strong acid- HCL
weak acid- ethanoic acid (XH)
what do the properties of an acid depend on
on the H+
HCL and XH reaction with Mg
HCL- hotter produce same vol. of H2 effervesces faster
CH3COOH - less hotter, same vol. of H2, effervesces
HCL and XH reaction with Na2CO3
HCL- no temp change, produce same vol. of H2, effervesces faster
CH3COOH- no temp. change, produce same vol. of H2, effervesces
HCL and XH reaction with NaOH
HCL- hotter
CH3COOH- less hotter
electrical conductivity with HCL and XH
HCL- effervesces at electrodes, 4amps
CH3COOH- effervesces electrodes, 2amps
titration
a method use to accurately determine the conc. of an acid or base
volumetric pipette
measure a specific volume very accurately
burette
measure a range of volumes less accurately
titration method
- clean pipette with water
- clean pipette with intended chemical
- measure 25cm3 of unknown solution into a conical flask
- add 2 drops of indicator
- clean burette with water and intended chemical
- fill burette with acid
- clamp vertically
- measure intial vol.
- add acid until solution turns colourless
methyl orange
acid- red
base- yellow
phenolphthalein
acid- colorless
base- pink
salt
an ionic compound that can be formed by the reaction of an acid
properties of salts
high melting point due to strong electrostatic forces
conduct elec. as (aq) and (l) bc ions can move and carry charge
soluble in water
solubility rules
all nitrates are soluble
all gp 1 compounds are soluble
all halides are soluble except with ag or Pb 2+
all sulfates are soluble except with Ca, Sr, Ba, Pb, Ra
all hydroxides, oxides, and carbonates are insoluble
precipitation
2 solutions reacting to form a solid
displacement
when a more reactive element replaces a less reactive one in its compound
how do you produce a salt that is pure
the base in the reacvtion need to be insoluble
method for salt preperation
- measure xcm3 of acid in a conical flask
- add excess base until solid no longer dissapears
- heat to speed reaction
- filter mixture into concial flask
- heat filtrate on hot plate until 3/4 of water has evaporated
- leave to crystallize
- filter to remove excess water
- collect residue