organic chem Flashcards

1
Q

What is crude oil and how is it formed?

A

Crude oil is a fossil fuel formed under the sea from the remains of tiny plants, animals, and bacteria over millions of years under high pressure and moderate temperatures, without oxygen.

Example sentence: Crude oil is extracted from underground reservoirs and refined to produce various petroleum products.

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2
Q

What is a hydrocarbon?

A

A hydrocarbon is a compound made of only hydrogen and carbon atoms.

Example sentence: Methane, the main component of natural gas, is a simple hydrocarbon.

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3
Q

How are the different components of crude oil separated?

A

Through fractional distillation, which separates hydrocarbons based on their boiling points.

Example sentence: The process of fractional distillation involves heating crude oil in a fractionating column.

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4
Q

What happens to hydrocarbons with higher boiling points during fractional distillation, and why?

A

They condense and are drawn off at the bottom of the fractionating column because they have longer chains and stronger intermolecular forces.

Example sentence: Heavy hydrocarbons like bitumen are collected at the bottom of the fractionating column.

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5
Q

Name some uses of the different fractions obtained from crude oil.

A

Refinery gas: Bottled gas for heating and cooking
Gasoline: Fuel for cars
Kerosene: Aircraft fuel
Diesel: Fuel for lorries and buses
Bitumen: Making roads

Example sentence: Gasoline is a vital fuel for internal combustion engines in vehicles.

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6
Q

What is the main use of hydrocarbons?

A

As fuels, which release heat energy when burned.

Example sentence: Hydrocarbons like propane are commonly used in gas-powered appliances for cooking and heating.

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7
Q

What is the difference between complete and incomplete combustion of hydrocarbons?

A

Complete combustion produces carbon dioxide and water, while incomplete combustion also produces carbon monoxide and soot due to limited oxygen.

Example sentence: Incomplete combustion of hydrocarbons can lead to the formation of harmful pollutants.

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8
Q

Why is carbon monoxide dangerous?

A

It is a colourless, odourless gas that reduces the blood’s capacity to carry oxygen, making it highly poisonous.

Example sentence: Carbon monoxide poisoning can result from exposure to exhaust fumes in enclosed spaces.

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9
Q

What environmental problems are associated with burning fossil fuels?

A

Greenhouse effect (global warming) and acid rain, due to the emission of carbon dioxide, sulfur dioxide, and nitrogen oxides.

Example sentence: The combustion of fossil fuels contributes to the increase in greenhouse gases in the atmosphere.

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10
Q

What is an alkane and what is its general formula?

A

Alkanes are saturated hydrocarbons (contain only single bonds) with the general formula CnH2n+2.

Example sentence: Methane and ethane are simple alkanes commonly found in natural gas.

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11
Q

What is the general formula for alkenes and what distinguishes them from alkanes?

A

Alkenes have the general formula CnH2n and contain at least one carbon-carbon double bond, making them unsaturated and more reactive than alkanes.

Example sentence: Ethene is an example of an alkene used in the production of polyethylene.

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12
Q

What is a substitution reaction in the context of alkanes?

A

In the presence of UV light, a hydrogen atom in an alkane is replaced by a halogen atom.

Example sentence: Chlorination of methane is a common substitution reaction involving the replacement of hydrogen atoms with chlorine atoms.

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13
Q

How can you distinguish between saturated and unsaturated hydrocarbons using bromine water?

A

Unsaturated hydrocarbons (alkenes) will decolourise bromine water, while saturated hydrocarbons (alkanes) will not.

Example sentence: The addition of bromine water to an alkene results in the disappearance of the orange-brown color.

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14
Q

What is an isomer?

A

Isomers are compounds with the same molecular formula but different structural arrangements of atoms.

Example sentence: Butane and isobutane are isomers with different structures but the same molecular formula.

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15
Q

What is cracking and why is it important?

A

Cracking is the process of breaking long-chain hydrocarbons into shorter, more useful ones (alkanes and alkenes), making the refining of crude oil more profitable.

Example sentence: Cracking is a crucial step in the petrochemical industry to maximize the yield of valuable products from crude oil.

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16
Q

What is polymerisation and what problem is associated with the disposal of polymers?

A

-Polymerisation is the process of joining monomers to form polymers.
-Polymers are non-biodegradable, causing pollution when disposed of in landfills or burned.

Example sentence: The polymerisation of ethylene leads to the formation of polyethylene, a commonly used plastic material.

17
Q

What are the two main methods of producing ethanol?

A
  1. Fermentation of sugars, which is a slower, batch process.
  2. Catalytic hydration of ethene, a faster, continuous process that produces pure ethanol.

Example sentence: Ethanol production through fermentation is widely used in the brewing and distilling industries.

18
Q

a) Write the word equation for the reaction between an alkene and steam to make ethenol
b) State the 3 conditions for this reaction

A

a) ethane+water=ethenol
C2H4+H2O=C2H6O

b)
-60-70 atm of pressure
-300 degrees
-concentrated phosphoric acid catalyst

19
Q

Draw a labelled diagram of the catalytic hydration of ethene

A

Check notivility organic chemistry

20
Q

a) Write the word and chemical equation for fermentation
b) State the conditions for this reaction

A

a)
Glucose->carbin dioxide+ethenol
C6H12O6 → 2CO2 + 2C2H5OH
b)
-anareobic conditions

21
Q

Draw a labelled diagram of how fermentation produces ethenol

A

chsck noitiblity

22
Q

What is the formula fpr an alcohol

A

CnH2n+1

23
Q

What os the difference between a repeat unit and a monomoer

A

repeat unit has no double bond, monomer does

24
Q

List the 6 fractions of crude oil when fractional distillating

A

refinery gas - bottle gas for heating
gasoline - fuel in cars
kerosine - used in oil stoves
diesel - fuel in diesel ships
fuel oil - fuel for ships
bitumen - making roads
(as you go down:
-increase boiling point
-increasing viscocity
-darker colour)

25
Q

Fuels obtained by fraction can cause impurities
Explain how the combustion of a common impurity in fuels can cause an environmental problem

A

-sulfur is the impurity
-when burnt produces sulfiur dioxide
-when evapourated, condenses and falls as acid rain
-this erodes soil

26
Q

WHat is the catalyst used in cracking

A

sillica or allumina