Optical Isomerism Flashcards
Optical Isomerism
Form of stereoisomerism occurring as a result of chirality in molecules
Chiral Carbon
Carbon in a compound with 4 different groups attached to it
Optical isomers of Alanine
Enantimors
Racemic Mixture
50/50 mixture of two enantimors
Properties of enantimors
Have an effect on plane polarised light
React wit other chiral carbons
Describe how separate samples of each enantiomers could be distinguished
Shine plane polarised light through the sample, the light would rotate in the opposite direction
Why are racemic mixtures optically inactive?
The two enantiomers cancel each others light rotating effect
How is a racemic mixture formed (racemate)?
C=C and C=O double bonds are planar, the products of the reactions that occur at the carbonyl group of aldehydes and ketones are enantiomers present as a racemic mixture
What mechanism creates optically active compounds?
Nucleophilic Addition