Optical Isomerism Flashcards

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1
Q

What does stereoisomer means

A

Same structural from but different arrangements of atoms in space

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2
Q

What is a chiral molecule

A

A molecule that has 4 different groups attached to the carbon

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3
Q

What are enantiomers

A

Two compounds that are optical isomers of each other

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4
Q

Why are enantiomers non superimposable

A

No matter which way you turn them they won’t overlap

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5
Q

How do you detect enantiomers

A

We use plane polarised light

Optically active isomers will rotate plane polarised lights

Optically active compounds will rotate the light clockwise and anti-clockwise by the same amount of degrees

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6
Q

What is a racemic mixture

A

Equal amount of each enantiomers

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7
Q

Why do racemates not rotate in plane polarised light

A

They rotate the same degree in opposite directions so they cancel out

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8
Q

Can c=c and c=o make racemic products

A

Yes, as they have planar profiles. The nucleotides can attack from the top or bottom, so there is an even chance

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