naming rules Flashcards

1
Q

Parent examples

A

Phenol, aniline, etc

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2
Q

Naming formula

A

Parent, subs, number subs

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3
Q

Cyclohexene plus Br2

A

Anti addn

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4
Q

Benzene plus Br2

A

No rxn bc benzene is aromatic

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5
Q

How to do a frost circle

A
  1. Draw a circle
  2. Draw polygon inside it
  3. Line for each corner
  4. Dotted line in middle
  5. Fill in e-

If paired and below center line- aromatic. If above- antiaromatic (very unstable)

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6
Q

If a compound doesn’t have a flat ring with overlapping p orbitals, it is

A

nonaromatic

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7
Q

if a compound has a flat ring with overlapping p orbitals but doesn’t have 4N+2 pi electrons, it is

A

Antiaromatic

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8
Q

A lone pair in a P orbital counts as

A

pi electrons

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9
Q

Benzylic position

A

Directly connected to benzene ring

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10
Q

NaCr2O7, H2SO4

A

Strong oxidizing agent (Alkane chain to CO2H)

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11
Q

H2O, Heat

A

SN1 Substitution reaction with OH

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12
Q

NaOH

A

SN2 substitution with OH

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13
Q

Concentrated H2SO4

A

E1 elimination

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14
Q

NaOH

A

E2 elimination

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15
Q

3H2, Ni, high pressure and temp

A

Turns benzene to cyclohexane

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16
Q

H2, Pt, low pressure and temp

A

Removes DB from vincyclic position

17
Q

Birch reduction

A

Na, MeOH, NH3- removes DB

18
Q

Birch mechanism (page 12)

19
Q

If EWG present with birch

A

Pi bonds paralell to group

20
Q

If EDG present with birch

A

Pi bonds intersect with group