Electrophiles, nucleophiles, leaving groups Flashcards
SN2
Nucleophile attacks from back
SN1
LLG than NA
E2
Base steals positively charged spot
E1
Base included
Hydrohalogenation
H goes to anti mark, halo goes to mark
Acid catalyzed hydration
H+ transfer, nuclear attack, H+ transfer (?)
Oxymercuration demurcuration
OH at anti mark,.
Wgat does hydroboration oxy use?
BH3, THF, H2O2, NaOH
Hydroboration oxy
Antimark addition of H2O, mark addition of H across 2x bond, syn addn. 2 BH3 bonds together
Catalytic Hydroboration
Addition of H2 across double bond gets rid of it
Halo and halohydrin
Cl2 and Br2 are added across double bond. Double bond grabs 1, then positive charge recruits another.
Halo and halohydrin f done in nucleuophilic solvent
, nucleophile may be added (so BR/H2O can have Br and OH added. OH would be mark.)