Module 3 Test Flashcards

1
Q

What 4 things did early philosophers believe matter was composed of?

A

Earth, water, air, and fire.

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2
Q

Why did Democritus’s ideas about matter go against other philosophers beliefs?

A

Because Democritus could not answer the question of “What holds the atoms together?”.

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3
Q

Why were Democritus’s ideas about matter widely rejected?

A

Aristotle rejected the notion of atoms because it went against his beliefs. Aristotle was very influential at this time so many continued to reject Democritus’s ideas as well.

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4
Q

What was the book A System of Chemical Philosophy published by John Dalton about?

A

Describes how Dalton revisited and revised Democritus’s ideas and worked to determine the mass ratios of the elements involved in the experiments Dalton conducted.

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5
Q

Who was John Dalton?

A

John Dalton was a schoolteacher in England that developed the modern atomic theory by reviving and revising Democritus’s ideas by his performed experiments.

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6
Q

Why do you think John Dalton is important in understanding atoms?

A

Because his modern atomic theory explains that the conservation of mass in chemical reactions is the result of the rearrangement of atoms during the reaction.

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7
Q

What is an atom?

A

An atom is the smallest particle of matter that retains the properties of the element.

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8
Q

How do we know atoms exist?

A

Many experiments have been conducted since Dalton’s time to prove that atoms exist.

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9
Q

What is a cathode ray tube for?

A

It is used to help researchers study the relationship between mass and charge.

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10
Q

What is an electron?

A

An electron is a negatively charged particle that is a part of all forms of matter.

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11
Q

Who is J.J. Thomson?

A

J.J. Thomson was the first to identify the first subatomic particle, the electron.

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12
Q

How did J.J. Thomson identify the electron?

A

He did this by determining the charge-to-mass ratio of the charged particle, then compared that ratio to other known ratios.

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13
Q

Which of Dalton’s theories did J.J. Thomson disprove?

A

Thomson disproved Dalton’s theories about atoms not being divisible. His discovered proved Dalton incorrect because atoms can be divided into smaller subatomic particles.

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14
Q

What did Ernest Rutherford prove?

A

Rutherford proved that Thomson’s plum pudding model was incorrect because it did not match the results of his Gold experiment.

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15
Q

What did Rutherford contribute to atomic theory?

A

His results from the gold experiment proved that an atom has a positive charge and mass contained in the center of the atom.

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16
Q

What did Rutherford discover?

A

He discovered that atoms have a nucleus and protons/

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17
Q

Who discovered the neutron?

A

James Chadwick

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18
Q

What are quarks?

A

The first experimental evidence for subatomic particles, subatomic particles that make up the composition of the structures for protons and neutrons

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19
Q

Who is Henry Moseley and what did he contribute to atomic theory?

A

He was an English scientist that discovered atomic number, which explains that the number of protons in an atom identifies it as an atom of a particular element.

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20
Q

What does periodicity have to do with how the periodic table is structured?

A

The periodic table is organized left-to-right and top-to-bottom by increasing atomic number. This pattern of order within the periodic table is called periodicity.

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21
Q

Where is the atomic number listed on an element on the periodic table?

A

The atomic number is listed to the left or on top of the element’s symbol on the periodic table.

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22
Q

Where is the atomic mass listed on an element on the periodic table?

A

The atomic mass is listed below the element’s chemical name at the bottom of each element on the periodic table.

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23
Q

What is an isotope?

A

An isotope is an atom with the same number of protons but different number of neutrons.

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24
Q

What is the law of definite proportions?

A

A chemical in a compound always contains the same elements in exactly the same proportions by weight or by mass.

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25
Q

What is the law of conservation of mass?

A

Mass cannot be created nor destroyed in chemical or physical changes.

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26
Q

What law does this prove?

NaCl= 39.34% of Na and 60.66% Cl 1:1 ratio of Na to Cl

A

The law of definite proportions

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27
Q

What law does this prove?

30 kg of wood + 1 kg of fire —> 28 kg of ashes + 3 kg of smoke

A

The law of conservation of mass

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28
Q

What is the law of multiple proportions?

A

When two elements combine to form two or more compounds, the mass of one element that combines with a given mass of the other is in the ratio of small whole numbers

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29
Q
What law does this prove?
                  CO CO2
Mass of C 12g 12g
Mass of O 16g 32g
Ratio C:0 1:1 1:2
A

The law of multiple proportions

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30
Q

What is a proton?

A

A subatomic particle that ha a positive charge and is found in the nucleus of an atom

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31
Q

What is a neutron?

A

A subatomic particle that has a neutral/ no electric charge and is found in the nucleus of an atom

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32
Q

What is an electron?

A

A subatomic particle that has a negative electric charge and is found in the electron cloud surrounding the nucleus

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33
Q

What did Democritus suggest?

A

Suggested “indivisible” pieces of matter called atomos (atoms)

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34
Q

What did Aristotle believe?

A

Believed that matter was composed of air, water, fire, and earth, this attacked Democritus’s ideas and halted the progress of the atom for over 2,000 years

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35
Q

What did Dalton do with Democritus’s beliefs?

A

Revised them and determined elements were made of one kind of atom and they could combine to form compounds

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36
Q

What did Dalton and Democritus agree on?

A

Atoms took the shape of solid spherical balls

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37
Q

What are some of Dalton’s atomic theory principles that are always true?

A

Atoms of different elements differ in their physical and chemical properties.

Atoms of different elements combine in simple, whole-number ratios to form compounds.

In chemical reactions, atoms are combined, separated, or rearranged but never created, destroyed, or changed.

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38
Q

In Thomson’s plum pudding model, what were the electrons?

A

The electrons were the negatively charged particles that “floated” through the pudding

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39
Q

In Thomson’s plum pudding model, what were the protons?

A

The protons were the positively charged pudding

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40
Q

What did Thomson discover?

A

Electrons

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41
Q

What did Thomson use to discover electrons?

A

The cathode ray tube

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42
Q

What did Rutherford discover?

A

Most of the atom is empty space with a nucleus in the center

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43
Q

What are the remaining principles of Dalton’s theory that were proved to be not always true?

A

All matter is composed of extremely small particles called atoms which cannot be subdivided, created, or destroyed.

Atoms of given elements differ in their physical and chemical properties.

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44
Q

Ernest Rutherford was a student of JJ Thomson. When he got his own lab, he took on 2 students: Hans Geiger and Ernest Marsden, along with one of Thomson’s students Niels Bohr. What was the name of their famous experiment?

A

Gold Foil Experiment

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45
Q

So in the plum pudding model of the atom, the “dough” was actually a ____ charged sea.

A

Positively

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46
Q

When they shoot alpha particles at the gold foil, where do most of them go?

A

Right through the foil as if nothing is there.

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47
Q

What would make the alpha particles bend away from the center?

A

They are deflected by other positively charged particles in the atom

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48
Q

What would make alpha particles bounce right back?

A

They hit a positively charged particle head on (like a billiard ball hitting another head on)

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49
Q

What is an alpha particle?

A

Positively charged radioactive particle

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50
Q

What were some problems with Rutherford’s model?

A

The model believed electrons orbit around the nucleus like planets around the sun.

Opposites attract, so the positively charged nucleus should attract the negatively charged electrons.

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51
Q

What was the main problems with Rutherford’s gold experiment?

A

He could not explain why the electrons do not crash into the nucleus.

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52
Q

Who tried to solve the question Rutherford could not answer?

A

Niels Bohr

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53
Q

How did Bohr try to solve Rutherford’s unsolvable question?

A

He proposed that electrons travel around the nucleus in specific energy levels that are each a certain distance from the nucleus

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54
Q

What did Bohr say that energy levels worked like?

A

Energy levels worked like rungs of a ladder

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55
Q

Why do energy levels work like rungs on a ladder?

A

You can only stand on the rungs, not in between the spaces.

In relation, electrons can only be in one energy level or another not in between.

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56
Q

What was the last subatomic particle to be discovered?

A

The neutron

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57
Q

Who discovered the neutron in 1932?

A

James Chadwick

58
Q

True or False: Many of these scientists were laughed at and dismissed because they were not taken seriously.

A

True

59
Q

What was the first thing Rutherford, Geiger, Marsden, and Bohr concluded from the gold foil experiment?

A

Most of the atom is empty space because alpha particles pass right through it.

60
Q

What did they conclude about the atom?

A

The atom has a small positively charged nucleus

61
Q

Is Rutherford’s model of the atom the final model that we use today?

A

Nope, our understanding of the atom continued to evolve (still to this day)

62
Q

What are the two ideas Democritus made that were commonly acknowledged?

A

Everything in the universe if made of atomos.

Atoms are dense, indestructible spheres

63
Q

What are the two events involved with Aristotle?

A

Everything was made of fire, water, earth, and air.

He halted the progress of the atom for over 2,000 years.

64
Q

Who has been called the “Father of Modern Chemistry”?

A

Antoine-Laurent de Lavoisier which related to his emphasis on careful experimentation

65
Q

What two important things did Lavoisier discover?

A

He discovered the law of conservation of mass and the element oxygen.

66
Q

Who published the “Atomic Theory of Matter” stating all matter is made of atoms?

A

John Dalton

67
Q

What are the common discoveries that Dalton made?

A

Atoms combine to form compounds.

All atoms of the same elements are alike.

68
Q

What did Planck discover?

A

He discovered that atoms and molecules emit and absorb different levels of energy in the form of electromagnetic radiation.

69
Q

What did Thomson propose?

A

He proposed that atoms have an overall + charge with - charged dispersed throughout.

70
Q

Who used the Brownian Motion to prove that atoms exist?

A

Einstein

71
Q

Who was known for his publication of “The Theory of Relativity”?

A

Einstein

72
Q

What did Milikan discover?

A

He discovered the exact charge of an e (electron)

73
Q

What experiment did Rutherford perform?

A

The Gold Foil Experiment

74
Q

What did Rutherford discover from his experiment?

A

The nucleus is mostly empty space

75
Q

Does the nucleus contain positive, neutral, or negative charged particle?

A

Positive charged particles

76
Q

What did Bohr conclude?

A

E (electrons) are located in specific energy levels like rungs on a ladder

77
Q

Who discovered the Quantum Mechanical Model to locate e (electrons)?

A

Schrodinger

78
Q

What did Schrodinger discover about e (electrons)?

A

E (electrons) do not move in set paths, they move in waves with no exact location

79
Q

Who proposed the Uncertainty Principle?

A

Heisenberg

80
Q

What did Heisenberg propose?

A

He proposed that you can never know the exact position or speed of an e (electron)

81
Q

What was the main discovery that Chadwick made?

A

The discovery of the neutron

82
Q

What did DeBrogli propose?

A

He proposed that electrons act like waves in a confined space

83
Q

What can these confined waves only have?

A

Confined waves can only have certain frequencies

84
Q

What do these certain frequencies from confined waves relate to?

A

They relate to the energy of the wave

85
Q

In atoms, what are the frequencies of the electrons related to?

A

The frequencies of electrons are related to the energy level the electron is found in

86
Q

What does electromagnetic radiation travel in?

A

Electromagnetic radiation travels in waves

87
Q

What do different types of electromagnetic radiation have?

A

They have different frequencies

88
Q

What does light have the properties of?

A

Light has the properties of both waves and particles

89
Q

What is the photoelectric effect?

A

It states certain frequencies of light cause electrons to be released when it strikes metal

90
Q

What is the ground state?

A

The state where atoms normally exist with electrons at the lowest possible energy levels, closest to the nucleus

91
Q

What is the excited state?

A

Electrons can gain energy and move to this state farther from the nucleus

92
Q

Is the excited state stable or unstable?

A

Unstable

93
Q

What does it mean that the excited state is unstable?

A

The electron will release energy and fall back to the ground state

94
Q

What does the energy released from the excited state correspond to?

A

The energy released corresponds to the energy difference between different orbitals in the atom

95
Q

When are different colors of light emitted?

A

Different colors of light are emitted at different energies

96
Q

What is an emission spectra?

A

The light released when an electron falls from an excited state to a ground state which is unique to that element

97
Q

What is the light released when an electron falls from an excited state to a ground state that is unique to that element?

A

Emission spectra

98
Q

What does an electron emit a characteristic wavelength of light?

A

When dropping from a higher energy state to a lower energy state

99
Q

What are electron orbitals?

A

Regions of high probability of finding electrons

100
Q

What do electron orbitals do?

A

They show where electrons are

101
Q

Different orbitals have different what?

A

They have different shapes and orientations

102
Q

What are the names of the electron orbitals?

A

S, p, d, and f orbitals

103
Q

How many orbitals does the s-orbital have?

A

1 orbital

104
Q

How many electrons can the s-orbital hold max?

A

2 electrons max

105
Q

What is the shape of the s-orbital?

A

Spherical shape

106
Q

How many orbitals does the p-orbital have?

A

3 orbitals

107
Q

How many electrons can the p-orbital hold max?

A

6 electrons max

108
Q

What is the shape of the p-orbital?

A

Dumbbell shape

109
Q

How many orbitals does the d-orbital have?

A

5 orbitals

110
Q

How many electrons can the d-orbital hold max?

A

10 electrons max

111
Q

What is the shape of the d-orbital?

A

Clover leaf shape with 1 donut shape orbital

112
Q

How many orbitals does the f-orbital have?

A

7 orbitals

113
Q

How many electrons can the f-orbital hold max?

A

14 electrons max

114
Q

What is the shape of the f-orbital?

A

Tetrahedral

115
Q

What does writing electron configurations do?

A

Show us where each electron is located

116
Q

What is the Pauli Exclusion Principle?

A

Only 2 electrons can be in the same orbital at a time

117
Q

What is the Aufbau Principle?

A

Electrons fill orbitals with the lowest energy first

118
Q

What is the Hund’s Rule?

A

Electrons will fill all the orbitals with the same energy level (n) and quantum numbers (l) singly before pairing begins

119
Q

What do orbital diagrams help us show?

A

They help us show how electrons fill orbitals

120
Q

What is long-hand notation?

A

Long-hand notation shows each orbital with the number of electrons that are in it as a superscript.

121
Q

What is short-hand notation?

A

Starts with the last noble gas prior to the atom you are writing then, adds only the electrons in orbitals that the noble gas does not have

122
Q

What is shorthand notation used for?

A

Shorthand notation is used for larger atoms.

123
Q

What is the present day model of the atom called?

A

Quantum model

124
Q

Why were electrons assigned 4 quantum numbers when dealing with the quantum model?

A

To define where it is located

125
Q

When using quantum numbers, what are we talking about most oftenly?

A

We are most often talking about the very last electron in the electron cloud.

126
Q

What is the first quantum number called?

A

The principal quantum number (n)

127
Q

What does the quantum number (n) correspond to?

A

It corresponds to the row number on the periodic table (between 1-7)

128
Q

What happens as n increases?

A

The electrons distance from the nucleus and energy increases

129
Q

What is the second quantum number called?

A

Angular Momentum Quantum Number (l)

130
Q

What does the quantum number (l) indicate?

A

Indicates shape

131
Q

What does l equal when dealing with the s-orbital?

A

l= 0

132
Q

What does l equal when dealing with the p-orbital?

A

l= 1

133
Q

What does l equal when dealing with the d-orbital?

A

l= 2

134
Q

What does l equal when dealing with the f-orbital?

A

l= 3

135
Q

What is the third quantum number called?

A

Magnetic Quantum Number (m)

136
Q

What does the quantum number (m) indicate?

A

Indicates the number and orientation of orbitals around the nucleus within a subshell (Can be from -l to +l
*When l=0, m=0)

137
Q

What is the fourth quantum number called?

A

Spin Quantum Number (s)

138
Q

What does the quantum number (s) indicate?

A

Indicates the orientation of an electrons magnetic field.

139
Q

What does the quantum number (s) tell you?

A

Whether or not the spin is positive or negative (Can be listed as +½ or -½ or also as ↑ or ↓)

140
Q

What does each quantum number work to do?

A

Each quantum number locates the location of an electron a little more specifically.