Mistakes 4 Flashcards

1
Q

noble gas configuration (3)

A

(1) aka noble gas notation (2) the element symbol of the last noble gas prior to that atom, in brackets, substitutes for the e- configuration up to that point (3) an abbreviated form of e- configuration

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2
Q

significance of s and p subshells

A

organic chemistry, the chemistry of carbon-containing compounds, which are central to biology, involve interactions mostly in the s and p domains. So, these are the most important subshell types to be familiar with.

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3
Q

Bohr model (3)

A

(1) electrons are drawn in orbits rather than orbitals (2) useful to explain reactivity and chemical bonding but (3) doesn’t give a very accurate depiction of how electrons are distributed in space around the nucleus

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4
Q

drawing a lewis diagram (#8)

A

(8) evaluate for formal charge and possible other shapes, in order to determine the applicability of the Lewis structure

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5
Q

acid vs base, regular definition (3)

A

(1) the former contains an excess of H+ ions (2) the latter contains an excess of OH- ions (3) or dissociates into such ions in solution

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6
Q

Balancing redox in acidic solution

A

After you balance O and H, then you add electrons

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7
Q

titration procedure (3)

A

the scientist (1) mixes the solution with excess titrant (2) filters and dries the precipitate (3) weighs the precipitate, subtracting the mass of the filter paper from the total mass

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8
Q

qualities of polymeric solids

A

most are semicrystalline, meaning they contain both crystalline and amorphous regions

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9
Q

electron affinity (2)

A

(1) how much energy is released if we add an e- to a neutral version of a given element (2) elements that are high in this, are prone to accept e-

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10
Q

sigma bond, qualities (2)

A

(1) there is free rotation about a sigma bond (2) which leads to different conformations, ie shapes, of the molecule

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11
Q

referencing e- affinity (2)

A

(1) when energy is released, e- affinity is said by convention to be negative (2) so a very negative e- affinity, and a high e- affinity, mean the same thing

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12
Q

caveat to e- affinity (2)

A

(1) in a given subshell, e- fill unfilled orbitals before completing partially filled ones (2) this causes minor variations/exceptions to the overall periodic trend for e- affinity

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13
Q

electron shielding (3)

A

(1) aka e- screening (2) the effect of inner/core electrons repelling outer electrons, thus (3) decreasing the effective nuclear charge

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14
Q

periodic trends (4)

A

(1) atomic radii (2) ionization energy (3) electron affinity (4) electronegativity (5) and effective nuclear charge

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15
Q

resonance structures vs isomers

A

(1) the former is when Lewis diagrams differ in the distribution of electrons (2) the latter is when compounds differ in the arrangement of the atoms themselves

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16
Q

steric number (3)

A

(1) sigma bonds plus lone pairs (2) determines molecular geometry, specifically the bond angle (3) determines the type of hybridization that occurs

17
Q

yield arrow (3)

A

(1) reactants go to the left of this, and products to the right of it (2) this is read as “yields” or (3) “reacts to form”

18
Q

reagent (2)

A

(1) a catalyst or titrant (2) sometimes used interchangeably with reactant, but that is incorrect

19
Q

OH- (2)

A

(1) aka “hydroxide”
(2) present in bases

20
Q

polarity (of a bond)

A

the difference in electronegativity between the two bonding atoms