Metals Flashcards

1
Q

what is malachite?

A

copper carbonate hydroxide

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2
Q

metals form giant regular [] where a sea of delocalised [] move freely

A

lattice
electrons

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3
Q

A metallic bond can be explained as

A

The attraction between the negative sea of electrons to the positive metal lattice

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4
Q

A metallic bond is [], therefore metals have [] boiling points

A

strong
high

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5
Q

A mixture of metals is called a

A

alloy

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6
Q

FCC stands for

A

Face centred cubic

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7
Q

HCP stands for

A

hexagonal close packed

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8
Q

BCC stands for

A

body centred cubic

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9
Q

in HCP, the atoms are layered in which kind of pattern?

A

ABA

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10
Q

in FCC, the atoms are layered in which kind of pattern?
What is the result of this?

A

CBA
all holes are filled

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11
Q

What are the types of imperfections in crystal structures?

A

substitutional atoms
intersticial atoms
vacancies
dislocation

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12
Q

What is a substitutional atom?

A

when different size foreign material is introduced

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13
Q

What is an intersticial atom?

A

an atom that is squeezed into uniform structure, causing local stresses

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14
Q

What is a vacancy?

A

a missing atom which causes a stress field in the missing reigon

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15
Q

What is a grain boundary?

A

it is the interface between adjacent crystalline reigons that have different orientation

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16
Q

what is intergranular fracture?

A

facture that may occur between grains

17
Q

What is a dislocation?

A

Extra line of atoms in a structure, makes for easier plastic deformation

18
Q

In plastic deformation, how does a dislocation move in a lattice structure?

A

the row of dislocations will be pushed along by a force
it will slip under the plane of atoms and move through the structure

19
Q

Under low [] dislocations move along the direction of []

A

shear
force

20
Q

What are the properties of alloys determined by?

A

composition of microstructure
distribution of phases
processing
size+shape of grain

21
Q

Steel is an alloy of mainly which materials?

A

iron
carbon(<2%)
silicon, phosphorous, sulphur, O2 (<1%)

22
Q

Grain boundaries are barriers to

A

dislocation motion

23
Q

The more [] sites, the more [].

A

nucleation sites
the more boundaries

(nucleation is the initial process of forming a crystal from a solution btw)

24
Q

Reduced grain size =

A

higher yield stress

25
solute atoms have an associated []
strain field
26
the associated strain field of atoms interacts with the strain field of nearby [] and inhibits []
dislocations motion
27
Plastic deformation increases the number and density of
dislocations
28
dislocations also increase in density in []. dislocations moving on intersecting slip planes [] and []
plastic flow pile up and tangle
29
precipitation strengthening requires a fine distribution of of [] phase particles
2nd
30
the 2nd phase particles used in precipitation strengthening have their very own [] that interacts with dislocations by [] and [] them
strain fields pinning and locking them
31
What is a phase diagram?
a diagram that depicts the relationships between different phases of a substance under varying conditions of temperature and composition
32
What will the phase diagram axes represent?
y axis - temperature x axis - composition % e.g wt% of C in a steel alloy
33
What does a tie line represent?
a horizontal line that connects two phases in equilibrium at a specific temperature and composition
34
What does the lever rule tell us?
determines the fraction of each phase present based on the ratio of lengths of the tie line when you bisect it with a point and want to know the ratio of phases present.
35
What is a eutectic point in a phase diagram?
specific composition and temperature at which a binary mixture undergoes a eutectic reaction.
36
what is a eutectic reaction?
The liquid phase transforms into two different solid phases at the same time