Ceramics Flashcards

1
Q

Ceramics can be defined as

A

inorganic, non-metallic materials

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2
Q

ceramics are typically [] with some [] phase

A

typically crystalline

with some glassy phase

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3
Q

Ceramics are formed with compounds such as:

A

Aluminium + oxygen
Calcium + oxygen
Silicon + nitrogen

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4
Q

What are some examples of ceramics?

A

Clay products - bricks,tiles

White wares - dinner ware, electrical porcelain

Glass - flat glass, glass fibres

Natural abrasives - for cutting

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5
Q

[] compressive strength

A

High

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6
Q

[] tensile strength

A

Low

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7
Q

[] toughness

A

Low

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8
Q

[] hardness

A

High

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9
Q

[] + [] insulation

A

Thermal + electrical

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10
Q

[] durability

A

Good

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11
Q

[] cost except for [] processes

A

Low cost

Thermal processes

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12
Q

Clays moulds in a [] state then []

A

In a plastic state

Then sintered

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13
Q

Clays are complex []

A

Hydrated aluminosilicates

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14
Q

What are some examples of clays (basically geotechnics)

A

Kaolinite
Montmorilonite
Feldspars
Quartz sand

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15
Q

Clays are rich in

A

Alumina, silica and water

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16
Q

What are the 6 types of clay minerals

A

Brick
Bentomite
Common
Fire
Fuller’s earth
Kaolin

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17
Q

Structure wetting or clay causes silicate layers to

A

Slide

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18
Q

In sintering ceramic powders typically have a size of

A

0.5-5μm

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19
Q

Clays are [] mixed with []

A

Minerals
Water

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20
Q

In liquid phase sintering, the glassy phase

A

Melts

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21
Q

In liquid phase sintering, liquid draws the solid together by [] flow, driven by [] pressure

A

Viscous flow

Capillary pressure

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22
Q

In liquid phase sintering, the liquid phase can cool to . . .

A

Glass or crystallise

23
Q

What are the some engineering ceramics?

A

Silicon nitride
Silicon carbide
Zirconium oxide

24
Q

What temp is sintering normally done at?

25
What happens to applied stress at tips of flaws in a ceramic?
Amplified
26
Which equations describes the tensile fracture stress of a ceramic
Griffith’s equation
27
What is involved in the first step of ceramic processing?
Slurry formation Moisture optimisation Spray drying
28
What is the effect of spray drying?
Dries ceramic slurry into spherical particles
29
What are the three choices in step two of ceramic processing? (shaping)
Powder processing Extrusion Slip casting
30
What happens in powder processing?
Powder poured into mould Mould is pressed
31
What happens in extrusion?
Dried slurry particles pushed through a small hole to bind them closer together ( like a toothpaste tube)
32
What happens in slip casting?
Water flows through particles, their mass draws the particles together
33
What is the third step of ceramic processing?
Drying
34
What is the final part of ceramic processing?
Sintering
35
The ceramic microstructure consists of
Crystalline phases Amorphous (glassy) phase Porosity
36
What is meant by amorphous?
Irregular, lacking a clearly defined form
37
Dislocations in ceramics are responsible for
Ductility
38
Pores/ surface flaws concentrate what?
Stress
39
Stress concentrating flaws are called
Griffith’s flaws
40
Ceramics are [] materials This gives them inherent [] durability
Oxidised materials Chemical durability
41
Which process is used for the mass production of disc shaped ceramic products?
Uni-axial pressing
42
Why are the four steps for uni-axial pressing?
Pouring Pressing Ejection Repetition
43
Briefly describe slip casting of ceramics
Slip/slurry poured into mould Excess water is extracted through porous calcium silicate/gypsum mould Finished piece is sintered
44
Before powder processing, the ceramic micro structure is
A granular powder
45
After powder processing, the ceramic micro structure is
A compacted green body
46
After sintering , the ceramic micro structure is
A ceramic component With grains sticking together
47
What is adobe?
Unrefined ceramic Sun dried mud blocks An ancient and popular material
48
What are the three main steps to brick production?
Clay is crushed and extruded Cut by wires Dried in a kiln
49
How do sintered products compare to chemically bonded materials
Inherently stronger
50
For what reasons might bricks fall apart?
Water absorption Repeated freeze thaw cycles Surfaces suffer from flaking/ spalling Mortars joints crumble due to frost failure
51
What is efflorescence of bricks?
The appearance of salts deposited on the surface of bricks that were dissolved in wet working conditions appear once dry
52
What is the iron staining of bricks?
Similar to efflorescence, only it is iron oxides that leech out instead of soluble salts Due to saturation of immature bricks
53
Explain lime staining
Occurs when work is left uncovered and exposed to rain