Glass Flashcards
What are the key properties of glass?
Transparent
High stiffness
Brittle
Strong in compression
Weak in tension
Hard
Fracture produces sharp surfaces
Excellent corrosion resistance
Low leaching of contaminants
What are the possible properties of glass composites
Improved tensile strength
Heat resistance
Noise dampening
High impact resistance
Light + heat transmission
What kind of material is glass?
Non-crystalline
Amorphous
How is glass produced from its liquid state?
Continuous cooling
What is the basic building block for glass?
SiO4 tetrahedron he’s together with covalent bonds
How does glass maintain its amorphous liquid phase structure?
By being supercooled into a solid
Why is glass higher in silica purity less viscous?
Less molecules disrupting structure
Increased viscosity [] ability to form a [] solid
Inhibits ability
Crystalline solid
What type of glass has the lowest viscosity?
Soda lime glass
How does alkali addition affect the microstructure of glass?
Breaks up the structure
Covalent bonding distances and angles break up the structure
As alkali are added, which kind of oxygen atoms form?
Ionic Non-bridging oxygen atoms
When referring to bridging oxygen atoms what does x mean in Qx
The number of bridging oxygens in the tetrahedron
Low levels of sodium give []
While higher ones give []
Q3
Q2
What does sodium saturation do to the SiO4 tetrahedron?
Make it unable to anything else
Oxygen bonds are broken
In the schematic microstructure of glass, which elements are network formers?
Si
Al
In the schematic microstructure of glass, which elements are network modifiers?
Na
Ca
What is a network modifier?
Breaks glass structure, causes amorphous form
What raw materials go into glass?
Glass sand
Alumina sand
Soda ash
Limestone
Dolomite
In commercial glass, SiO2 makes up how much?
70-74%