Mats Lecture 10 Flashcards

Materials and Energy

1
Q

Recall what the different types of energy are?

A

-Mechanical
-Chemical
-electrical
-Heat/thermal
-Nuclear
-Light/radiant

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2
Q

Why is heat so important to material behaviour?

A

-Most processes require a certain amount of work to be done
-Heat usually provides most of the energy to do the work

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3
Q

Describe what latent heat is

A

-the energy required for a phase change

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4
Q

What is latent heat typically associated with?

A

-The change in entropy (randomness) of the atomic arrangement

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5
Q

Describe what sensible heat is and why it is important

A

-the vibration of atoms
-At Absolute Zero (0k/-273 degrees Celsius), atoms in a solid begin to oscillate

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6
Q

What is the Boltzmann constant?

A

-Kb
-is the proportionality factor that relates the average relative kinetic energy of particles in a gas with the thermodynamic temperature of the gas

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7
Q

How is thermal energy stored in materials? relate this to a spring metaphor for bonds

A

-Atomic vibration stretches one spring and compresses the other

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8
Q

When is energy at a max?

A

-When Δa is at a max

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9
Q

When is energy at a min?

A

When Δa is equal to zero

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10
Q

What is the definition of binding energy?

A

The minimum energy required to create or break a bond

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11
Q

What is the definition of Heat Capacity?

A

-is a material property that characterizes the amount of energy required to increase the temperature of a given mass of that material

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12
Q

What happens to materials when they are heated?

A

-They expand

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13
Q

On an atomic level, what happens when atoms are heated?

A

-The amplitude of atomic vibrations increases when atoms are heated
-The atoms vibrate about an increasing mean spacing

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14
Q

What do stronger bonds mean graphically?

A

-A steeper force-spacing curve
-a deeper energy well meaning less expansion (a lower CTE)

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15
Q

What do stronger bonds imply?

A

-Higher Young’s Modulus
-Higher Melting Temperature

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16
Q

Define what Thermal Conductivity means

A

-The rate at which heat is conducted through a solid under steady state conditions

17
Q

List the ways that heat is transmitted through solids

A
  1. Thermal Vibrations (all materials)
  2. The motion of free electrons (metals)
  3. Radiation (transparent materials)
18
Q

What are thermal vibrations also known as?

A

phonons

19
Q

what are thermal vibrations?

A

-are elastic waves that travel at the speed of sound

20
Q

What is thermal diffusivity?

A

-Heat flow in transient conditions (temperature that changes with time)

21
Q

How is thermal diffusivity measured?

A

-By subjecting one end of a material to a heat pulse (aka by a laser) and measuring the TIME it takes for the temperature rise to be sensed at the other end

22
Q

What does thermal expansion depend on?

A

-on the strength and stiffness of the atomic bonds

23
Q

How can you manipulate the volumetric Heat Capacity of a material?

A

-Foaming (reducing the density) is the only approach
-volumetric Heat Capacity is constant for all materials