Lipids Flashcards
3 classifications of fatty acid
Saturated fatty acids
Monounsaturated fatty acids
Polysunsaturated fatty acid
Omega 3 fatty acids
- double bond between 3rd and 4th carbon atoms
- walnuts, seeds, oily fish
- lowers blood pressure and boosts brain activity
Cis fatty acid
- naturally occurring
-eg olive oil - reduce risk of CHD
Hydrogens are on same side of the double bond
Trans fatty acid
- man made
- eg cakes, pastry’s
- increase LDL cholesterol
- hydrogens are on different side of double bond
Properties
Smoke point Plasticity Hydrogenation Emulsion Rancidity Ether
Smoke point
- solid fat eg butter is heated to 30-60’C it melts
= if heated to 200’C fat or 250’C oil the glycerol separates from the fatty acid
= changes to acrolein which produces a blue haze and smoke
Flash point- overheating causing vapour to spontaneously ignite and burst into flames - occurs at 310’C fat or 325’C oil
Plasticity
How solid/liquid or separable that fat is
Eg butter is hard but margarine is soft and more plastic and more user friendly when baking
Hydrogenation
Hydrogen is added to unsaturated fat with nickel catalyst present in it.
- converting oil into fats and use in production margarine
= create trans fats
Emulsion
Created when two liquids that don’t normally mix are forced together eg oil and vinegar
=water in oil emulsion
-eg butter 80% fat and 16% water
=oil in water emulsion
-eg milk 4% fat and 87% water
Two types emulsion
Temporary emulsion- eg shaking a french dressing to mix vinegar and oil
Permanent emulsion- eg lechtin in egg yolk used as a emulsifier added to mayonnaise
Rancidity
= spoilage of lipids
- Oxidative rancidity - oxygen combines with the carbon at double bond
- Hydroltyic rancidity- enzymes or bacteria break down fats changing them into fatty acids and glycerol
Ether
Fat is soluble in ether
Liver
- produces bile containing salt
- bile salts breakdown lipids to emulsifier fats
Pancreas
- produces pancreatic juice containing pancreatic lipid
- this breaks lipid into 1 glycerol and 3 fatty acids
Small intestine
- produces intestinal juice containing intestinal lipase
- completes digestion of fats