Lipids Flashcards

1
Q

3 classifications of fatty acid

A

Saturated fatty acids
Monounsaturated fatty acids
Polysunsaturated fatty acid

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2
Q

Omega 3 fatty acids

A
  • double bond between 3rd and 4th carbon atoms
  • walnuts, seeds, oily fish
  • lowers blood pressure and boosts brain activity
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3
Q

Cis fatty acid

A
  • naturally occurring
    -eg olive oil
  • reduce risk of CHD
    Hydrogens are on same side of the double bond
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4
Q

Trans fatty acid

A
  • man made
  • eg cakes, pastry’s
  • increase LDL cholesterol
  • hydrogens are on different side of double bond
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5
Q

Properties

A
Smoke point 
Plasticity 
Hydrogenation 
Emulsion
Rancidity 
Ether
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6
Q

Smoke point

A
  • solid fat eg butter is heated to 30-60’C it melts
    = if heated to 200’C fat or 250’C oil the glycerol separates from the fatty acid
    = changes to acrolein which produces a blue haze and smoke
    Flash point- overheating causing vapour to spontaneously ignite and burst into flames
  • occurs at 310’C fat or 325’C oil
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7
Q

Plasticity

A

How solid/liquid or separable that fat is

Eg butter is hard but margarine is soft and more plastic and more user friendly when baking

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8
Q

Hydrogenation

A

Hydrogen is added to unsaturated fat with nickel catalyst present in it.
- converting oil into fats and use in production margarine
= create trans fats

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9
Q

Emulsion

A

Created when two liquids that don’t normally mix are forced together eg oil and vinegar
=water in oil emulsion
-eg butter 80% fat and 16% water
=oil in water emulsion
-eg milk 4% fat and 87% water

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10
Q

Two types emulsion

A

Temporary emulsion- eg shaking a french dressing to mix vinegar and oil

Permanent emulsion- eg lechtin in egg yolk used as a emulsifier added to mayonnaise

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11
Q

Rancidity

A

= spoilage of lipids

  1. Oxidative rancidity - oxygen combines with the carbon at double bond
  2. Hydroltyic rancidity- enzymes or bacteria break down fats changing them into fatty acids and glycerol
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12
Q

Ether

A

Fat is soluble in ether

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13
Q

Liver

A
  • produces bile containing salt

- bile salts breakdown lipids to emulsifier fats

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14
Q

Pancreas

A
  • produces pancreatic juice containing pancreatic lipid

- this breaks lipid into 1 glycerol and 3 fatty acids

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15
Q

Small intestine

A
  • produces intestinal juice containing intestinal lipase

- completes digestion of fats

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16
Q

Saturated fatty acid

A
  • each carbon fully saturated with full quota of hydrogen atoms
  • no double bonds
17
Q

Monounsaturated fatty acid

A
  • reach carbon not fully saturated with full quota of hydrogen atoms
  • one double bond between carbons
18
Q

Polyunsaturated fatty acid

A
  • each carbon not saturated with a full quota of hydrogen atoms
  • more than one double bonds occurring between carbon atoms
19
Q

Emulsifier

A

Molecule that has hydrophilic head (water loving) and a hydrophobic tail (water hating)
= when added to mixture head attaches to water and tail attaches to oil
= prevent liquid from separating
Eg lechtin in egg yolk used as emulsifier in mayonnaise