Lipids Flashcards
Biomolecules that stores energy
Lipids
Lipids are ____ in organic solvents and ____ in water.
Soluble, insoluble
____ lipids are those that can be converted to smaller moleculed by hydrolysis
Hydrolyzable or saponifiable
Structurally, most hydrolyzable lipids contains ____ unit.
A. Ether
B. Ester
C. Hydroxyl
D. Carboxyl
B
Esters from a high molecular weight alcohol and fatty acid. Very hydrophobic and presents water loss in plants
Waxes
Most abundant among lipids. Commonly known as fats and oils, as triesters of glycerol and fatty acids
Triacyclglycerols/Triglycerides (TAGS)
List the name of the ff saturated C10-C20 Fatty acids
C10
C12
C14
C16
C18
C20
Capric
Lauric
Myristic
Palmitic
Stearic
Arachidic
Lipids from animal sources. Forms straight chains, more compact and has higher MP
Saturated Fatty Acids
Lipids from plant sources. It has one or more double bonds, less compact and has lower MP
Unsaturated fatty acid
True or false. In saturated fatty acid, the higher the number of carbons, the melting point decreases
False. MP also increase
In unsaturated fatty acids, as the number of double bond increases, the melting point decreases.
True
True or false. The degree of unsaturation of oil depends on the average number of double bonds in it’s fatty acid
True
Fatty acid with two or more double bonds are called ____
Polyunsaturated Fatty Acid (PUFA)
Naturally occuring mono unsaturated fatty acid contains less than 10 carbons including crotonic acid.
False. 10 or more w/ exception crotonic acid
PUFA’s must be in trans (E) configuration.
False. Cis (Z)
Identify which among the following are the omega 3 fatty acids and omega 6 fatty acids.
- Arachidonic acid
- Eicosapentanoic acid
- Alpha-linoleic acid
- Linoleic acid
- Docosahexaenoic acid
- Omega 6 FA
- Omega 3 FA
- Omega 3 FA
- Omega 6 FA
- Omega 3 FA
These FA should be supplied through diets. Includes omega 3 and omega 6 FA
Essential FA
The ideal ratio of omega-3 and omega-6 in diet is _____ to _____
1:3 to 1:5
Organic derivatives of phosphoric acid, formed by replacing two H by R group.
Phospholipids
____ are phospholipids derived from glycerol while _____ are derived from sphingosine
Phosphoacylglycerols
Sphingomyelins
Second most abundant type of lipids
Phosphoacylglycerols
Two types of phosphoacylglycerols: phosphatidylethanolamine or _____ (-CH2CH2NH3^+) and phosphotidylcholine or ______ (-CH2CH2N(CH3)3^+).
Cephalin, lecithin
Lipids that cannot be broken down into simpler units by aqueous hydrolysis
Non hydrolyzable lipids
Identify the ff.
Vit. A
Vit. D
Vit. E
Vit. K
Retinol
Cholecalciferol
Tocopherol
Phylloquinone
Biologically active compound derived from arachidonic acid
Eicosanoids
Lipids composed of repeating units of isoprene
Terpenes
Biologically active tetracyclic lipids: three 6-membered ring and one 5-membered ring
Steroids
Steroids secreted by the endocrine glands. Further classified as adrenal cortical steroids.
Hormones
Cholesterol is synthesized in the body from ____ , a C30 triterpene
Squalene
Cholesterol is synthesized in the body from ____ , a C30 triterpene
Squalene