Lipids Flashcards
Lipids
Organic compounds including fats and oils.
Triglycerides
Fats and oils are esters called triglycerides. Triglycerides are a type of liquid - consisting of a glycerol molecule bonded to three long chain carboxylic acids called fatty acids. Triglycerides are formed through a condensation reaction and are non-polar.
Fatty acids
Can be saturated (no double bonds between carbons) or unsaturated (double bonds)
Oils contain more unsaturated fatty acids than fats (fats are solid at room temp and oils are liquid)
Glycerol + Fatty Acid
Triglyceride molecule + H2O
Hydrogen from glycerol and OH from fatty acid form H2O
Saponification
A triglyceride is hydrolysed with a strong base to form glycerol and fatty acid salts (reverse of condensation reaction)
The salts dissociate to form carboxylate ions - soap molecules
Carboxylate ions are made up of a long hydrophobic tail (non-polar) and a hydrophilic head (polar)
The tails of the carboxylate ions gather together and the heads face outwards towards the water
Tails attract oil particles, heads interact with water
The cleaning action of soap in hard water is impaired because
The hydrophilic ends react with calcium ions to form insoluble salts